A New Facile Route for the Preparation of Single-Source Precursors for Bulk, Thin-Film, and Nanocrystallite I−III−VI Semiconductors

A New Facile Route for the Preparation of Single-Source Precursors for Bulk, Thin-Film, and Nanocrystallite I−III−VI Semiconductors

We report a new simplified synthetic procedure for commercial manufacture of ternary single-source precursors (SSPs). This new synthetic process has been successfully implemented to fabricate known SSPs on bulk scale and the first liquid SSPs to the semiconductors CuInSe2 and AgIn x S y . Single cry...

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Veröffentlicht in:Inorganic chemistry 2003-12, Vol.42 (24), p.7713-7715
Hauptverfasser: Banger, Kulbinder K, Jin, Michael H.-C, Harris, Jerry D, Fanwick, Philip E, Hepp, Aloysius F
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container_end_page 7715
container_issue 24
container_start_page 7713
container_title Inorganic chemistry
container_volume 42
creator Banger, Kulbinder K
Jin, Michael H.-C
Harris, Jerry D
Fanwick, Philip E
Hepp, Aloysius F
description We report a new simplified synthetic procedure for commercial manufacture of ternary single-source precursors (SSPs). This new synthetic process has been successfully implemented to fabricate known SSPs on bulk scale and the first liquid SSPs to the semiconductors CuInSe2 and AgIn x S y . Single crystal X-ray determination reveals the first unsolvated ternary AgInS SSP. SSPs prepared via this new route have successfully been used in a spray assisted chemical vapor deposition (CVD) process to deposit polycrystalline thin films, and for preparing ternary nanocrystallites.
doi_str_mv 10.1021/ic034802h
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title A New Facile Route for the Preparation of Single-Source Precursors for Bulk, Thin-Film, and Nanocrystallite I−III−VI Semiconductors
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