Dynamic behavior of the Jahn-Teller distorted Cu(H(2)O)(6)(2+) ion in Cu(2+) doped Cs(2)[Zn(H(2)O)(6)](ZrF(6))(2) and the crystal structure of the host lattice
The temperature dependence of the X- and Q-band EPR spectra of Cs(2)[Zn(H(2)O)(6)](ZrF(6))(2) containing approximately 1% Cu(2+) is reported. All three molecular g-values vary with temperature, and their behavior is interpreted using a model in which the potential surface of the Jahn-Teller distorte...
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| Veröffentlicht in: | Inorganic chemistry 2002-01, Vol.41 (2), p.229-238 |
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| container_title | Inorganic chemistry |
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| creator | Hitchman, Michael A Yablokov, Yurii V Petrashen, Vladimir E Augustyniak-Jabłokov, Maria A Stratemeier, Horst Riley, Mark J Łukaszewicz, Kazimierz Tomaszewski, Paweł E Pietraszko, Adam |
| description | The temperature dependence of the X- and Q-band EPR spectra of Cs(2)[Zn(H(2)O)(6)](ZrF(6))(2) containing approximately 1% Cu(2+) is reported. All three molecular g-values vary with temperature, and their behavior is interpreted using a model in which the potential surface of the Jahn-Teller distorted Cu(H(2)O)(6)(2+) ion is perturbed by an orthorhombic "strain" induced by interactions with the surrounding lattice. The strain parameters are significantly smaller than those reported previously for the Cu(H(2)O)(6)(2+) ion in similar lattices. The temperature dependence of the two higher g-values suggests that in the present compound the lattice interactions change slightly with temperature. The crystal structure of the Cs(2)[Zn(H(2)O)(6)](ZrF(6))(2) host is reported, and the geometry of the Zn(H(2)O)(6)(2+) ion is correlated with lattice strain parameters derived from the EPR spectrum of the guest Cu(2+) complex. |
| format | Article |
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The crystal structure of the Cs(2)[Zn(H(2)O)(6)](ZrF(6))(2) host is reported, and the geometry of the Zn(H(2)O)(6)(2+) ion is correlated with lattice strain parameters derived from the EPR spectrum of the guest Cu(2+) complex.</description><issn>0020-1669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><recordid>eNpFkF9LwzAUxfuguDn9CpInaZFC_nRd-ijTOWWwlz1NpKTJDY20TU1SYZ_Gr2qnDp8O5_K793DuWTTFmOKU5HkxiS69f8cYFyzLL6IJIRzjnJBp9PVw6ERrJKqgFp_GOmQ1CjWgF1F36Q6aBhxSxgfrAii0HOJ1TJNtEudJTO8SZGyHTHecH52y_RHyI_K67_7Rt3jvVqOOOwkSnfpJkO7gg2iQD26QYXBwiq6tD6gRIRgJV9G5Fo2H6z-dRbvV4265Tjfbp-fl_Sbt5xlJpaAazzOeaS0yzkAWlRJSUsgVZrqo9BwYKZiivOJUcuBKS7GgOidYsUJlbBbd_p7tnf0YwIeyNV6O7UUHdvDlgjBOMGUjePMHDlULquydaYU7lKePsm-MNWzz</recordid><startdate>20020128</startdate><enddate>20020128</enddate><creator>Hitchman, Michael A</creator><creator>Yablokov, Yurii V</creator><creator>Petrashen, Vladimir E</creator><creator>Augustyniak-Jabłokov, Maria A</creator><creator>Stratemeier, Horst</creator><creator>Riley, Mark J</creator><creator>Łukaszewicz, Kazimierz</creator><creator>Tomaszewski, Paweł E</creator><creator>Pietraszko, Adam</creator><scope>NPM</scope><scope>7X8</scope></search><sort><creationdate>20020128</creationdate><title>Dynamic behavior of the Jahn-Teller distorted Cu(H(2)O)(6)(2+) ion in Cu(2+) doped Cs(2)[Zn(H(2)O)(6)](ZrF(6))(2) and the crystal structure of the host lattice</title><author>Hitchman, Michael A ; Yablokov, Yurii V ; Petrashen, Vladimir E ; Augustyniak-Jabłokov, Maria A ; Stratemeier, Horst ; Riley, Mark J ; Łukaszewicz, Kazimierz ; Tomaszewski, Paweł E ; Pietraszko, Adam</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p541-ca2f05484ffa483ec9bdacc2e6d03f9bf5e3193d28b82c8e8dfca72f610d39d43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hitchman, Michael A</creatorcontrib><creatorcontrib>Yablokov, Yurii V</creatorcontrib><creatorcontrib>Petrashen, Vladimir E</creatorcontrib><creatorcontrib>Augustyniak-Jabłokov, Maria A</creatorcontrib><creatorcontrib>Stratemeier, Horst</creatorcontrib><creatorcontrib>Riley, Mark J</creatorcontrib><creatorcontrib>Łukaszewicz, Kazimierz</creatorcontrib><creatorcontrib>Tomaszewski, Paweł E</creatorcontrib><creatorcontrib>Pietraszko, Adam</creatorcontrib><collection>PubMed</collection><collection>MEDLINE - Academic</collection><jtitle>Inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hitchman, Michael A</au><au>Yablokov, Yurii V</au><au>Petrashen, Vladimir E</au><au>Augustyniak-Jabłokov, Maria A</au><au>Stratemeier, Horst</au><au>Riley, Mark J</au><au>Łukaszewicz, Kazimierz</au><au>Tomaszewski, Paweł E</au><au>Pietraszko, Adam</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dynamic behavior of the Jahn-Teller distorted Cu(H(2)O)(6)(2+) ion in Cu(2+) doped Cs(2)[Zn(H(2)O)(6)](ZrF(6))(2) and the crystal structure of the host lattice</atitle><jtitle>Inorganic chemistry</jtitle><addtitle>Inorg Chem</addtitle><date>2002-01-28</date><risdate>2002</risdate><volume>41</volume><issue>2</issue><spage>229</spage><epage>238</epage><pages>229-238</pages><issn>0020-1669</issn><abstract>The temperature dependence of the X- and Q-band EPR spectra of Cs(2)[Zn(H(2)O)(6)](ZrF(6))(2) containing approximately 1% Cu(2+) is reported. All three molecular g-values vary with temperature, and their behavior is interpreted using a model in which the potential surface of the Jahn-Teller distorted Cu(H(2)O)(6)(2+) ion is perturbed by an orthorhombic "strain" induced by interactions with the surrounding lattice. The strain parameters are significantly smaller than those reported previously for the Cu(H(2)O)(6)(2+) ion in similar lattices. The temperature dependence of the two higher g-values suggests that in the present compound the lattice interactions change slightly with temperature. The crystal structure of the Cs(2)[Zn(H(2)O)(6)](ZrF(6))(2) host is reported, and the geometry of the Zn(H(2)O)(6)(2+) ion is correlated with lattice strain parameters derived from the EPR spectrum of the guest Cu(2+) complex.</abstract><cop>United States</cop><pmid>11800611</pmid><tpages>10</tpages></addata></record> |
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| title | Dynamic behavior of the Jahn-Teller distorted Cu(H(2)O)(6)(2+) ion in Cu(2+) doped Cs(2)[Zn(H(2)O)(6)](ZrF(6))(2) and the crystal structure of the host lattice |
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