Stereoselective biosynthesis of chloroarylpropane diols by the basidiomycete Bjerkandera adusta: exploring the roles of amino acids, pyruvate, glycerol and phenyl acetyl carbinol

Bjerkandera adusta produces many chlorometabolites including chlorinated anisyl metabolites (CAMs) and 1-arylpropane-1,2-diols ( 1, 2, 3, 4) as idiophasic metabolic products of L-phenylalanine. These diols are stereoselectively biosynthesized from a C 7-unit (benzylic, from L-phenylalanine) and a C...

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Veröffentlicht in:	FEMS microbiology letters 2003-11, Vol.228 (1), p.11-19
Hauptverfasser:	Silk, Peter James, Macaulay, John B
Format:	Artikel
Sprache:	eng
Schlagworte:	acetaldehyde acetates Acetone - analogs & derivatives Acetone - metabolism Amino Acids - metabolism Basidiomycota - metabolism Benzaldehydes - metabolism Biological and medical sciences Biosynthesis Bjerkandera adusta chlorination Chloroarylpropane diol chloroarylpropane diols Chlorometabolite enantiomers ethanol fluorine Fundamental and applied biological sciences. Psychology fungi Glucose - metabolism Glycerol Glycerol - metabolism glycols Hydrocarbons, Aromatic - chemistry Hydrocarbons, Aromatic - metabolism Hydrocarbons, Chlorinated - chemistry Hydrocarbons, Chlorinated - metabolism Ketol mass spectrometry metabolites methionine Microbiology Miscellaneous Molecular Conformation Mycology oxygen Phenyl acetyl carbinol phenylacetylcarbinol phenylalanine propane Pyruvate Pyruvate decarboxylase pyruvic acid Pyruvic Acid - metabolism serine serine dehydratase Stable isotope stereochemistry transamination
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