Stereocontrolled reactions mediated by a remote sulfoxide group: synthesis of optically pure anti-beta-amino alcohols

Stereocontrolled reactions mediated by a remote sulfoxide group: synthesis of optically pure anti-beta-amino alcohols

[reaction: see text] A one-step synthesis of enantiomerically pure anti-1,2-amino alcohol derivatives has been achieved by reaction of prochiral oxygenated 2-p-tolylsulfinylbenzyl carbanions with N-sulfinylimines bearing the same configuration at sulfur.

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Veröffentlicht in:Organic letters 2003-11, Vol.5 (23), p.4513-4516
Hauptverfasser: García Ruano, José L, Alemán, José
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container_title Organic letters
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creator García Ruano, José L
Alemán, José
description [reaction: see text] A one-step synthesis of enantiomerically pure anti-1,2-amino alcohol derivatives has been achieved by reaction of prochiral oxygenated 2-p-tolylsulfinylbenzyl carbanions with N-sulfinylimines bearing the same configuration at sulfur.
doi_str_mv 10.1021/ol0358410
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title Stereocontrolled reactions mediated by a remote sulfoxide group: synthesis of optically pure anti-beta-amino alcohols
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