Complexation with albumins of chiral aromatic substrates and their chemistry in ground and excited states. Catalytic and chirality recognition properties of the protein in the cases of binaphthol, its photoisomers, and ketoprofen

The reactivity of organic molecules can be modified upon complexation with proteins: these changes can be different and more significant when the substrate is in an electronically excited state. Here we review UV, CD, and fluorescence spectroscopy studies on the photochemistry and on the chemistry o...

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Veröffentlicht in:	Chirality (New York, N.Y.) N.Y.), 2002, Vol.14 (1), p.1-11
Hauptverfasser:	Ouchi, Akihiko, Zandomeneghi, Giorgia, Zandomeneghi, Maurizio
Format:	Artikel
Sprache:	eng
Schlagworte:	activation energy Animals atropisomers Binding Sites BSA catalysis Cattle CD spectroscopy Circular Dichroism fluorescence frequency factor Humans Hydrocarbons, Iodinated Hydrogen-Ion Concentration In Vitro Techniques Ketoprofen - chemistry Macromolecular Substances Naphthols - chemistry Photochemistry photochromism photoresolution Serum Albumin - chemistry Serum Albumin, Bovine - chemistry Spectrometry, Fluorescence Spectrophotometry, Ultraviolet Stereoisomerism Thermodynamics
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