The Dual Roles of Oxodiperoxovanadate Both as a Nucleophile and an Oxidant in the Green Oxidation of Benzyl Alcohols or Benzyl Halides to Aldehydes and Ketones

The Dual Roles of Oxodiperoxovanadate Both as a Nucleophile and an Oxidant in the Green Oxidation of Benzyl Alcohols or Benzyl Halides to Aldehydes and Ketones

One catalyst, two roles: VO(O2)2− reacts as a nucleophilic oxidant under acidic conditions towards benzyl alcohols. Altogether 15 alcohols have been oxidized, in the absence of organic solvent, in excellent yields. Benzyl halides are also oxidized by H2O2 in water catalyzed by oxodiperoxovanadate an...

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Veröffentlicht in:Angewandte Chemie International Edition 2003-10, Vol.42 (41), p.5063-5066
Hauptverfasser: Li, Chunbao, Zheng, Pengwu, Li, Jie, Zhang, Hang, Cui, Yi, Shao, Qiyun, Ji, Xiujie, Zhang, Jian, Zhao, Pengying, Xu, Yanli
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alcohols
green chemistry
oxidation
vanadium
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container_end_page 5066
container_issue 41
container_start_page 5063
container_title Angewandte Chemie International Edition
container_volume 42
creator Li, Chunbao
Zheng, Pengwu
Li, Jie
Zhang, Hang
Cui, Yi
Shao, Qiyun
Ji, Xiujie
Zhang, Jian
Zhao, Pengying
Xu, Yanli
description One catalyst, two roles: VO(O2)2− reacts as a nucleophilic oxidant under acidic conditions towards benzyl alcohols. Altogether 15 alcohols have been oxidized, in the absence of organic solvent, in excellent yields. Benzyl halides are also oxidized by H2O2 in water catalyzed by oxodiperoxovanadate and a phase transfer catalyst into aromatic aldehydes and ketones (see scheme). This reaction is the first green oxidation of benzyl halides.
doi_str_mv 10.1002/anie.200351902
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subjects alcohols
green chemistry
oxidation
vanadium
title The Dual Roles of Oxodiperoxovanadate Both as a Nucleophile and an Oxidant in the Green Oxidation of Benzyl Alcohols or Benzyl Halides to Aldehydes and Ketones
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