Catalytic asymmetric synthesis of 1,1'-spirobi[indan-3,3'-dione] via a double intramolecular C-H insertion process
A highly efficient one-pot construction of optically active 1,1'-spirobi[indan-3,3'-dione] derivative (up to 80% ee) has been achieved by exploiting the double intramolecular C-H insertion reaction of dimethyl 2,2'-methylenebis(alpha-diazo-beta-oxobenzenepropanoate) under the influenc...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2001 (17), p.1604-1605 |
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| container_end_page | 1605 |
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| container_issue | 17 |
| container_start_page | 1604 |
| container_title | Chemical communications (Cambridge, England) |
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| creator | Takahashi, T Tsutsui, H Tamura, M Kitagaki, S Nakajima, M Hashimoto, S |
| description | A highly efficient one-pot construction of optically active 1,1'-spirobi[indan-3,3'-dione] derivative (up to 80% ee) has been achieved by exploiting the double intramolecular C-H insertion reaction of dimethyl 2,2'-methylenebis(alpha-diazo-beta-oxobenzenepropanoate) under the influence of dirhodium(II) tetrakis[N-phthaloyl-(R or S)-tert-leucinate] as a catalyst. |
| doi_str_mv | 10.1039/b103747c |
| format | Article |
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| ispartof | Chemical communications (Cambridge, England), 2001 (17), p.1604-1605 |
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| source | Royal Society of Chemistry Journals Archive (1841-2007); Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Catalytic asymmetric synthesis of 1,1'-spirobi[indan-3,3'-dione] via a double intramolecular C-H insertion process |
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