Coated-Wire Silver Ion-Selective Electrode Based on Silver Complex of Cyclam
A coated-wire ion-selective electrode (ISE) based on cyclam (1,4,8,11-tetraazacyclotetradecane) as a neutral carrier in a polyvinyl chloride (PVC) matrix was fabricated for the determination of Ag(I) ions. The coated-wire ISE exhibited a linear Nernstian response over the range 1 × 10-1 to 1 × 10-7...
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| Veröffentlicht in: | Analytical Sciences 2001, Vol.17(4), pp.477-479 |
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| creator | SIL, Aparna IJERI, Vijaykumar S. SRIVASTAVA, Ashwini K. |
| description | A coated-wire ion-selective electrode (ISE) based on cyclam (1,4,8,11-tetraazacyclotetradecane) as a neutral carrier in a polyvinyl chloride (PVC) matrix was fabricated for the determination of Ag(I) ions. The coated-wire ISE exhibited a linear Nernstian response over the range 1 × 10-1 to 1 × 10-7 M with a slope of 59 ± 2 mV per decade change and a detection limit of 5 × 10-8 M. The ISE shows a greater preference for Ag over other cations with good precision. The electrode was selective towards Ag(I) ions in the presence of 13 different metal ions tested. The selectivity coefficients (Kij) were determined for Na(I), K(I), Mg(II), Ca(II), Ba(II), Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II), Pb(II) and Hg(II). The selectivity coefficients of these cations are in the range of 10-4 to 10-2. This ISE was used for the determination of free silver and total silver in electroplating bath solutions, additives and brighteners. |
| doi_str_mv | 10.2116/analsci.17.477 |
| format | Article |
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The coated-wire ISE exhibited a linear Nernstian response over the range 1 × 10-1 to 1 × 10-7 M with a slope of 59 ± 2 mV per decade change and a detection limit of 5 × 10-8 M. The ISE shows a greater preference for Ag over other cations with good precision. The electrode was selective towards Ag(I) ions in the presence of 13 different metal ions tested. The selectivity coefficients (Kij) were determined for Na(I), K(I), Mg(II), Ca(II), Ba(II), Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II), Pb(II) and Hg(II). The selectivity coefficients of these cations are in the range of 10-4 to 10-2. This ISE was used for the determination of free silver and total silver in electroplating bath solutions, additives and brighteners.</description><identifier>ISSN: 0910-6340</identifier><identifier>EISSN: 1348-2246</identifier><identifier>DOI: 10.2116/analsci.17.477</identifier><identifier>PMID: 11990560</identifier><identifier>CODEN: ANSCEN</identifier><language>eng</language><publisher>Tokyo: The Japan Society for Analytical Chemistry</publisher><subject>Analytical chemistry ; Cations ; Chemistry ; Electrochemistry ; Electrodes ; Electrodes: preparations and properties ; Electroplating ; Exact sciences and technology ; General and physical chemistry ; General, instrumentation ; Ion selective electrodes ; Lead ; Nickel ; Polyvinyl chloride ; Silver</subject><ispartof>Analytical Sciences, 2001, Vol.17(4), pp.477-479</ispartof><rights>2001 by The Japan Society for Analytical Chemistry</rights><rights>2001 INIST-CNRS</rights><rights>Copyright Japan Science and Technology Agency 2001</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c599t-b7ce8ee7d28b61af8395ce18cec0e3f81f58490200825624f18183c513b0bc63</citedby><cites>FETCH-LOGICAL-c599t-b7ce8ee7d28b61af8395ce18cec0e3f81f58490200825624f18183c513b0bc63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,1877,4010,27904,27905,27906</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=974440$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/11990560$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>SIL, Aparna</creatorcontrib><creatorcontrib>IJERI, Vijaykumar S.</creatorcontrib><creatorcontrib>SRIVASTAVA, Ashwini K.</creatorcontrib><title>Coated-Wire Silver Ion-Selective Electrode Based on Silver Complex of Cyclam</title><title>Analytical Sciences</title><addtitle>Anal Sci</addtitle><description>A coated-wire ion-selective electrode (ISE) based on cyclam (1,4,8,11-tetraazacyclotetradecane) as a neutral carrier in a polyvinyl chloride (PVC) matrix was fabricated for the determination of Ag(I) ions. The coated-wire ISE exhibited a linear Nernstian response over the range 1 × 10-1 to 1 × 10-7 M with a slope of 59 ± 2 mV per decade change and a detection limit of 5 × 10-8 M. The ISE shows a greater preference for Ag over other cations with good precision. The electrode was selective towards Ag(I) ions in the presence of 13 different metal ions tested. The selectivity coefficients (Kij) were determined for Na(I), K(I), Mg(II), Ca(II), Ba(II), Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II), Pb(II) and Hg(II). The selectivity coefficients of these cations are in the range of 10-4 to 10-2. This ISE was used for the determination of free silver and total silver in electroplating bath solutions, additives and brighteners.</description><subject>Analytical chemistry</subject><subject>Cations</subject><subject>Chemistry</subject><subject>Electrochemistry</subject><subject>Electrodes</subject><subject>Electrodes: preparations and properties</subject><subject>Electroplating</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>General, instrumentation</subject><subject>Ion selective electrodes</subject><subject>Lead</subject><subject>Nickel</subject><subject>Polyvinyl chloride</subject><subject>Silver</subject><issn>0910-6340</issn><issn>1348-2246</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><recordid>eNpdkE1P4zAQhq0VaCndvXJEkZC4pXhsJ7GPEPFRqdIeqLRHy3EmkMqJi50i-PekarfAXsYjzTPzWg8hZ0BnDCC_Mr1x0bYzKGaiKH6QCXAhU8ZEfkQmVAFNcy7oCTmNcUUpMMnYT3ICoBTNcjohi9KbAev0bxsweWzdK4Zk7vv0ER3aoX3F5HbbBF9jcmMi1onv_3Gl79YO3xLfJOW7dab7RY6b8Tv4e_9OyfLudlk-pIs_9_PyepHaTKkhrQqLErGomaxyMI3kKrMI0qKlyBsJTSaFooxSybKciQYkSG4z4BWtbM6n5HJ3dh38ywbjoLs2WnTO9Og3URfAgaqxTsnFf-DKb8LWmAYhZMZFJthIzXaUDT7GgI1eh7Yz4V0D1VvJei9ZQ6FHyePC-f7spuqw_sT3Vr_kmmiNa4LpbRsPnCqEEFuq3FGrOJgnPIxNGFrr8Fvqrozhh6l9NkFjzz8AcBecVQ</recordid><startdate>2001</startdate><enddate>2001</enddate><creator>SIL, Aparna</creator><creator>IJERI, Vijaykumar S.</creator><creator>SRIVASTAVA, Ashwini K.</creator><general>The Japan Society for Analytical Chemistry</general><general>Japan Society for Analytical Chemistry</general><general>Japan Science and Technology Agency</general><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SE</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>H8G</scope><scope>JG9</scope><scope>L7M</scope><scope>P64</scope><scope>7X8</scope></search><sort><creationdate>2001</creationdate><title>Coated-Wire Silver Ion-Selective Electrode Based on Silver Complex of Cyclam</title><author>SIL, Aparna ; IJERI, Vijaykumar S. ; SRIVASTAVA, Ashwini K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c599t-b7ce8ee7d28b61af8395ce18cec0e3f81f58490200825624f18183c513b0bc63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><topic>Analytical chemistry</topic><topic>Cations</topic><topic>Chemistry</topic><topic>Electrochemistry</topic><topic>Electrodes</topic><topic>Electrodes: preparations and properties</topic><topic>Electroplating</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>General, instrumentation</topic><topic>Ion selective electrodes</topic><topic>Lead</topic><topic>Nickel</topic><topic>Polyvinyl chloride</topic><topic>Silver</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>SIL, Aparna</creatorcontrib><creatorcontrib>IJERI, Vijaykumar S.</creatorcontrib><creatorcontrib>SRIVASTAVA, Ashwini K.</creatorcontrib><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Analytical Sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>SIL, Aparna</au><au>IJERI, Vijaykumar S.</au><au>SRIVASTAVA, Ashwini K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Coated-Wire Silver Ion-Selective Electrode Based on Silver Complex of Cyclam</atitle><jtitle>Analytical Sciences</jtitle><addtitle>Anal Sci</addtitle><date>2001</date><risdate>2001</risdate><volume>17</volume><issue>4</issue><spage>477</spage><epage>479</epage><pages>477-479</pages><issn>0910-6340</issn><eissn>1348-2246</eissn><coden>ANSCEN</coden><abstract>A coated-wire ion-selective electrode (ISE) based on cyclam (1,4,8,11-tetraazacyclotetradecane) as a neutral carrier in a polyvinyl chloride (PVC) matrix was fabricated for the determination of Ag(I) ions. The coated-wire ISE exhibited a linear Nernstian response over the range 1 × 10-1 to 1 × 10-7 M with a slope of 59 ± 2 mV per decade change and a detection limit of 5 × 10-8 M. The ISE shows a greater preference for Ag over other cations with good precision. The electrode was selective towards Ag(I) ions in the presence of 13 different metal ions tested. The selectivity coefficients (Kij) were determined for Na(I), K(I), Mg(II), Ca(II), Ba(II), Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II), Pb(II) and Hg(II). The selectivity coefficients of these cations are in the range of 10-4 to 10-2. This ISE was used for the determination of free silver and total silver in electroplating bath solutions, additives and brighteners.</abstract><cop>Tokyo</cop><pub>The Japan Society for Analytical Chemistry</pub><pmid>11990560</pmid><doi>10.2116/analsci.17.477</doi><tpages>3</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Analytical chemistry Cations Chemistry Electrochemistry Electrodes Electrodes: preparations and properties Electroplating Exact sciences and technology General and physical chemistry General, instrumentation Ion selective electrodes Lead Nickel Polyvinyl chloride Silver |
| title | Coated-Wire Silver Ion-Selective Electrode Based on Silver Complex of Cyclam |
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