Direct Oxidation of Benzene to Phenol with Hydrogen Peroxide over a Modified Titanium Silicalite
Stopping the rot! The selective oxidation of benzene to phenol with hydrogen peroxide is achieved by using a new zeolite catalyst (TS‐1B), obtained by the modification of titanium silicalite with NH4HF2 and H2O2 (see scheme). The new catalyst, used in presence of a particular cosolvent (sulfolane) p...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2003-10, Vol.42 (40), p.4937-4940 |
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| container_issue | 40 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Balducci, Luigi Bianchi, Daniele Bortolo, Rossella D'Aloisio, Rino Ricci, Marco Tassinari, Roberto Ungarelli, Raffaele |
| description | Stopping the rot! The selective oxidation of benzene to phenol with hydrogen peroxide is achieved by using a new zeolite catalyst (TS‐1B), obtained by the modification of titanium silicalite with NH4HF2 and H2O2 (see scheme). The new catalyst, used in presence of a particular cosolvent (sulfolane) protects the produced phenol from overoxidation and dramatically enhances the selectivity of the reaction. |
| doi_str_mv | 10.1002/anie.200352184 |
| format | Article |
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The selective oxidation of benzene to phenol with hydrogen peroxide is achieved by using a new zeolite catalyst (TS‐1B), obtained by the modification of titanium silicalite with NH4HF2 and H2O2 (see scheme). 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The selective oxidation of benzene to phenol with hydrogen peroxide is achieved by using a new zeolite catalyst (TS‐1B), obtained by the modification of titanium silicalite with NH4HF2 and H2O2 (see scheme). The new catalyst, used in presence of a particular cosolvent (sulfolane) protects the produced phenol from overoxidation and dramatically enhances the selectivity of the reaction.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>14579444</pmid><doi>10.1002/anie.200352184</doi><tpages>4</tpages></addata></record> |
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| subjects | benzene hydroxylation solvent effects titanium zeolites |
| title | Direct Oxidation of Benzene to Phenol with Hydrogen Peroxide over a Modified Titanium Silicalite |
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