Cupric Decamolybdodivanadophosphate. A Coordination Polymer Heterogeneous Catalyst for Rapid, High Conversion, High Selectivity Sulfoxidation Using the Ambient Environment

A new type of coordination network polymer involving the redox-active polyanion, PV2Mo10O40 5-, and bridging −CuII(OH2)4− units, {[(CuII(OH2)4)3(OH)]PV2Mo10O40} n (1), has been characterized by X-ray crystallography and several other methods. It is the first efficient heterogeneous (insoluble) catal...

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Veröffentlicht in:Inorganic chemistry 2003-10, Vol.42 (21), p.6610-6612
Hauptverfasser: Okun, Nelya M, Anderson, Travis M, Hardcastle, Kenneth I, Hill, Craig L
Format: Artikel
Sprache:eng
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