Generation of the Enol of Methyl Mandelate by Flash Photolysis of Methyl Phenyldiazoacetate in Aqueous Solution and Study of Rates of Ketonization of This Enol in That Medium

Flash photolysis of methyl phenyldiazoacetate in aqueous solution produced phenylcarbomethoxycarbene, whose hydration generated a short-lived transient species that was identified as the enol isomer of methyl mandelate. This assignment is supported by the shape of the rate profile for decay of the e...

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Veröffentlicht in:	Journal of organic chemistry 2000-02, Vol.65 (4), p.1175-1180
Hauptverfasser:	Chiang, Y, Kresge, A. J, Schepp, N. P, Xie, R.-Q
Format:	Artikel
Sprache:	eng
Schlagworte:	Azo Compounds - chemistry Azo Compounds - metabolism Buffers Catalysis Hydrocarbons Ketones - chemistry Ketones - metabolism Kinetics Mandelic Acids - chemistry Mandelic Acids - metabolism Methane - analogs & derivatives Methane - chemistry Methane - metabolism Phenylacetates - chemistry Phenylacetates - metabolism Photolysis Solutions Water - metabolism
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