Determination of trace elements in quartz glass by use of LINA-Spark-ICP-MS as a new method for bulk analysis of solid samples
The determination of trace elements in pure quartz glass samples has been performed by coupling an ICP quadrupole mass spectrometer with the LINA-Spark-Atomizer, an IR laser ablation system dedicated to direct bulk and surface analysis of solid samples. Linear calibration curves were obtained for ni...
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| Veröffentlicht in: | Analytical and bioanalytical chemistry 2001-07, Vol.370 (5), p.521-526 |
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| description | The determination of trace elements in pure quartz glass samples has been performed by coupling an ICP quadrupole mass spectrometer with the LINA-Spark-Atomizer, an IR laser ablation system dedicated to direct bulk and surface analysis of solid samples. Linear calibration curves were obtained for nine elements (Na, Al, Ca, Ti, Cr, Mn, Zr, Ba, and Pb) in the ng g(-1) range with detection limits of less than 10 ng g(-1) for Ca, Cr, Mn, Zr, Ba, and Pb and in the range of 120-220 ng g(-1) for Na, Al, and Ti. The distance between the laser focal point and the sample surface has a significant influence on signal intensity and precision, both of which can be improved by a factor of approximately two by focusing the laser 15 mm behind the sample surface. Aerosol moistening reduced the standard deviation of the signal intensity by a factor of 2-4. Signal instability, which resulted from different ablation rates or variations in the transmission of the mass spectrometer, were compensated by use of the simultaneously measured SiAr+ ion as an internal standard. Under these conditions precision was usually better than 5% RSD. The results were compared with those obtained by use of a commercial LA-ICP-MS system. With this instrumentation linear calibration curves were achieved for three elements only (Al, Ti, and Pb), showing that LA-ICP-MS is less appropriate for bulk analysis in the ng g(-1) range. |
| doi_str_mv | 10.1007/s002160100789 |
| format | Article |
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Linear calibration curves were obtained for nine elements (Na, Al, Ca, Ti, Cr, Mn, Zr, Ba, and Pb) in the ng g(-1) range with detection limits of less than 10 ng g(-1) for Ca, Cr, Mn, Zr, Ba, and Pb and in the range of 120-220 ng g(-1) for Na, Al, and Ti. The distance between the laser focal point and the sample surface has a significant influence on signal intensity and precision, both of which can be improved by a factor of approximately two by focusing the laser 15 mm behind the sample surface. Aerosol moistening reduced the standard deviation of the signal intensity by a factor of 2-4. Signal instability, which resulted from different ablation rates or variations in the transmission of the mass spectrometer, were compensated by use of the simultaneously measured SiAr+ ion as an internal standard. Under these conditions precision was usually better than 5% RSD. The results were compared with those obtained by use of a commercial LA-ICP-MS system. With this instrumentation linear calibration curves were achieved for three elements only (Al, Ti, and Pb), showing that LA-ICP-MS is less appropriate for bulk analysis in the ng g(-1) range.</description><identifier>ISSN: 0937-0633</identifier><identifier>ISSN: 1618-2642</identifier><identifier>EISSN: 1432-1130</identifier><identifier>EISSN: 1618-2650</identifier><identifier>DOI: 10.1007/s002160100789</identifier><identifier>PMID: 11496981</identifier><language>eng</language><publisher>Berlin: Springer</publisher><subject>Ablation ; Aluminum ; Analytical chemistry ; Atomizing ; Barium ; Bulk sampling ; Calcium ; Calibration ; Chemistry ; Detection limits ; Exact sciences and technology ; Instrumentation ; Laser ablation ; Lasers ; Lead ; Manganese ; Quadrupoles ; Quartz ; Silica glass ; Sodium ; Spectrometric and optical methods ; Surface analysis (chemical) ; Titanium ; Trace elements ; Zirconium</subject><ispartof>Analytical and bioanalytical chemistry, 2001-07, Vol.370 (5), p.521-526</ispartof><rights>2001 INIST-CNRS</rights><rights>Springer-Verlag Berlin Heidelberg 2001.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c346t-97c3d06699b2192bbf6fa3a7208f89abebcbe6ee706a8dcc6dab54b492c152f63</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>309,310,314,776,780,785,786,23910,23911,25119,27903,27904</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=1094074$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/11496981$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>TIBI, Markus</creatorcontrib><creatorcontrib>HEUMANN, Klaus G</creatorcontrib><title>Determination of trace elements in quartz glass by use of LINA-Spark-ICP-MS as a new method for bulk analysis of solid samples</title><title>Analytical and bioanalytical chemistry</title><addtitle>Fresenius J Anal Chem</addtitle><description>The determination of trace elements in pure quartz glass samples has been performed by coupling an ICP quadrupole mass spectrometer with the LINA-Spark-Atomizer, an IR laser ablation system dedicated to direct bulk and surface analysis of solid samples. Linear calibration curves were obtained for nine elements (Na, Al, Ca, Ti, Cr, Mn, Zr, Ba, and Pb) in the ng g(-1) range with detection limits of less than 10 ng g(-1) for Ca, Cr, Mn, Zr, Ba, and Pb and in the range of 120-220 ng g(-1) for Na, Al, and Ti. The distance between the laser focal point and the sample surface has a significant influence on signal intensity and precision, both of which can be improved by a factor of approximately two by focusing the laser 15 mm behind the sample surface. Aerosol moistening reduced the standard deviation of the signal intensity by a factor of 2-4. Signal instability, which resulted from different ablation rates or variations in the transmission of the mass spectrometer, were compensated by use of the simultaneously measured SiAr+ ion as an internal standard. Under these conditions precision was usually better than 5% RSD. The results were compared with those obtained by use of a commercial LA-ICP-MS system. With this instrumentation linear calibration curves were achieved for three elements only (Al, Ti, and Pb), showing that LA-ICP-MS is less appropriate for bulk analysis in the ng g(-1) range.</description><subject>Ablation</subject><subject>Aluminum</subject><subject>Analytical chemistry</subject><subject>Atomizing</subject><subject>Barium</subject><subject>Bulk sampling</subject><subject>Calcium</subject><subject>Calibration</subject><subject>Chemistry</subject><subject>Detection limits</subject><subject>Exact sciences and technology</subject><subject>Instrumentation</subject><subject>Laser ablation</subject><subject>Lasers</subject><subject>Lead</subject><subject>Manganese</subject><subject>Quadrupoles</subject><subject>Quartz</subject><subject>Silica glass</subject><subject>Sodium</subject><subject>Spectrometric and optical methods</subject><subject>Surface analysis (chemical)</subject><subject>Titanium</subject><subject>Trace 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methods</topic><topic>Surface analysis (chemical)</topic><topic>Titanium</topic><topic>Trace elements</topic><topic>Zirconium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>TIBI, Markus</creatorcontrib><creatorcontrib>HEUMANN, Klaus G</creatorcontrib><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and 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Academic</collection><jtitle>Analytical and bioanalytical chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>TIBI, Markus</au><au>HEUMANN, Klaus G</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Determination of trace elements in quartz glass by use of LINA-Spark-ICP-MS as a new method for bulk analysis of solid samples</atitle><jtitle>Analytical and bioanalytical chemistry</jtitle><addtitle>Fresenius J Anal Chem</addtitle><date>2001-07-01</date><risdate>2001</risdate><volume>370</volume><issue>5</issue><spage>521</spage><epage>526</epage><pages>521-526</pages><issn>0937-0633</issn><issn>1618-2642</issn><eissn>1432-1130</eissn><eissn>1618-2650</eissn><abstract>The determination of trace elements in pure quartz glass samples has been performed by coupling an ICP quadrupole mass spectrometer with the LINA-Spark-Atomizer, an IR laser ablation system dedicated to direct bulk and surface analysis of solid samples. Linear calibration curves were obtained for nine elements (Na, Al, Ca, Ti, Cr, Mn, Zr, Ba, and Pb) in the ng g(-1) range with detection limits of less than 10 ng g(-1) for Ca, Cr, Mn, Zr, Ba, and Pb and in the range of 120-220 ng g(-1) for Na, Al, and Ti. The distance between the laser focal point and the sample surface has a significant influence on signal intensity and precision, both of which can be improved by a factor of approximately two by focusing the laser 15 mm behind the sample surface. Aerosol moistening reduced the standard deviation of the signal intensity by a factor of 2-4. Signal instability, which resulted from different ablation rates or variations in the transmission of the mass spectrometer, were compensated by use of the simultaneously measured SiAr+ ion as an internal standard. Under these conditions precision was usually better than 5% RSD. The results were compared with those obtained by use of a commercial LA-ICP-MS system. With this instrumentation linear calibration curves were achieved for three elements only (Al, Ti, and Pb), showing that LA-ICP-MS is less appropriate for bulk analysis in the ng g(-1) range.</abstract><cop>Berlin</cop><pub>Springer</pub><pmid>11496981</pmid><doi>10.1007/s002160100789</doi><tpages>6</tpages></addata></record> |
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| subjects | Ablation Aluminum Analytical chemistry Atomizing Barium Bulk sampling Calcium Calibration Chemistry Detection limits Exact sciences and technology Instrumentation Laser ablation Lasers Lead Manganese Quadrupoles Quartz Silica glass Sodium Spectrometric and optical methods Surface analysis (chemical) Titanium Trace elements Zirconium |
| title | Determination of trace elements in quartz glass by use of LINA-Spark-ICP-MS as a new method for bulk analysis of solid samples |
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