(Salen)Mn(III)-Catalyzed Epoxidation Reaction as a Multichannel Process with Different Spin States. Electronic Tuning of Asymmetric Catalysis:  A Theoretical Study

The (salen)Mn(III)-catalyzed epoxidation reaction mechanism has been investigated using density functional theory (DFT). There is considerable interest in and controversy over the mechanism of this reaction. The results of experimental studies have offered some support for three different reaction m...

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Veröffentlicht in:	Inorganic chemistry 2001-07, Vol.40 (16), p.4040-4048
Hauptverfasser:	Abashkin, Yuri G, Collins, Jack R, Burt, Stanley K
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Epoxy Compounds - chemistry Ethylenediamines - chemistry Free Radical Scavengers - chemistry Manganese - chemistry Models, Chemical Models, Theoretical Molecular Structure Organometallic Compounds - chemistry Stereoisomerism
Online-Zugang:	Volltext
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