In situ X-ray diffraction and solid-state NMR study of the fluorination of gamma-Al(2)O(3) with HCF(2)Cl

In situ X-ray diffraction (XRD) and NMR methods were used to follow the structural changes that occur during the dismutation reaction of hydrochlorofluorocarbon-22 (CHClF(2)) over gamma-alumina. Use of a flow cell allowed diffraction patterns to be recorded, while the reaction products were simultan...

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Veröffentlicht in:Journal of the American Chemical Society 2001-02, Vol.123 (8), p.1694-1702
Hauptverfasser: Chupas, P J, Ciraolo, M F, Hanson, J C, Grey, C P
Format: Artikel
Sprache:eng
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