Inverted meso-Aryl Porphyrins with Heteroatoms; Characterization of Thia, Selena, and Oxa N-Confused Porphyrins

Synthesis and characterization of inverted porphyrins containing S, Se, and O are reported. A simple 3 + 1 MacDonald-type condensation using modified tripyrrane containing the N-confused ring and diols afforded various N-confused porphyrins 6a-f in 19-30% yield. The single-crystal X-ray structure of...

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Veröffentlicht in:Journal of organic chemistry 2001-01, Vol.66 (1), p.153-161
Hauptverfasser: PUSHPAN, Simi K., SRINIVASAN, Alagar, ANAND, Venkataramana Rao G., CHANDRASHEKAR, Tavarekere K., SUBRAMANIAN, Arunachalam, ROY, Raja, SUGIURA, Ken-ichi, SAKATA, Yoshiteru
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Sprache:eng
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