First Total Synthesis of Mosin B

The first total synthesis of mosin B and a diastereomer was accomplished using asymmetric desymmetrization of the σ-symmetric diol and the Nozaki−Hiyama−Kishi reaction as the key steps. The THF core segment was stereoselectively constructed employing a stereodivergent synthesis starting from a commo...

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Veröffentlicht in:	Organic letters 2001-02, Vol.3 (3), p.429-432
Hauptverfasser:	Maezaki, Naoyoshi, Kojima, Naoto, Sakamoto, Atsunobu, Iwata, Chuzo, Tanaka, Tetsuaki
Format:	Artikel
Sprache:	eng
Schlagworte:	Antineoplastic Agents, Phytogenic - chemical synthesis Furans - chemical synthesis Lactones - chemical synthesis Magnetic Resonance Spectroscopy Molecular Conformation Plants, Medicinal - chemistry Stereoisomerism Trees - chemistry
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