Intramolecular Hydrosilylation and Silicon-Assisted Cross-Coupling:  An Efficient Route to Trisubstituted Homoallylic Alcohols

Alkylidenesilacyclopentanes (formed by intramolecular hydrosilylation of homopropargyl alcohols) are efficiently coupled with aryl or alkenyl halides in the presence of tetrabutylammonium fluoride and a palladium(0) catalyst. Yields of cross-coupling were generally high, and the reaction is compatib...

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Veröffentlicht in:	Organic letters 2001-01, Vol.3 (1), p.61-64
Hauptverfasser:	Denmark, Scott E, Pan, Weitao
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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