Photo Amidoglycosylation of an Allal Azidoformate. Synthesis of β-2-Amido Allopyranosides

Photolysis of an allal C-3 azidoformate provoked intramolecular nitrene insertion into the glycal CC unit and allowed direct incorporation of alcohol nucleophiles as β-disposed substituents at C-1. The 2-amido allopyranoside products were elaborated via N-acylation and selective oxazolidinone hydro...

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Veröffentlicht in:	Organic letters 2001-02, Vol.3 (3), p.381-384
Hauptverfasser:	Kan, Cindy, Long, Charli M, Paul, Moushumi, Ring, Christina M, Tully, Sarah E, Rojas, Christian M
Format:	Artikel
Sprache:	eng
Schlagworte:	Amides - chemistry Azides - chemistry Carbohydrate Conformation Formates - chemistry Glycosides - chemical synthesis Glycosylation Photolysis
Online-Zugang:	Volltext
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