Photochemistry and Photophysics of Triarylmethane Dye Leuconitriles
The photochemical reactions of crystal violet leuconitrile (CVCN) were investigated by the means of product analysis and trapping experiments, laser flash and steady-state photolysis, and steady-state fluorescence. The influence of oxygen on the reaction was examined in detail. The photochemistry of...
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| Veröffentlicht in: | Journal of organic chemistry 2001-02, Vol.66 (3), p.659-671 |
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| container_end_page | 671 |
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| container_title | Journal of organic chemistry |
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| creator | Jarikov, Viktor V Neckers, Douglas C |
| description | The photochemical reactions of crystal violet leuconitrile (CVCN) were investigated by the means of product analysis and trapping experiments, laser flash and steady-state photolysis, and steady-state fluorescence. The influence of oxygen on the reaction was examined in detail. The photochemistry of malachite green leuconitrile (MGCN), basic fuchsin leuconitrile (BFCN), and crystal violet leucomethyl (CVMe) and leucobenzyl (CVBn), as well as triphenylacetonitrile, was studied. The results suggest ionization occurs from S1, while the di-π-methane reaction is the photochemical route from T1. |
| doi_str_mv | 10.1021/jo000374a |
| format | Article |
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The influence of oxygen on the reaction was examined in detail. The photochemistry of malachite green leuconitrile (MGCN), basic fuchsin leuconitrile (BFCN), and crystal violet leucomethyl (CVMe) and leucobenzyl (CVBn), as well as triphenylacetonitrile, was studied. 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| title | Photochemistry and Photophysics of Triarylmethane Dye Leuconitriles |
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