Di- and Trinuclear Complexes with the Mono- and Dianion of 2,6-Bis(phenylamino)pyridine:  High-Field Displacement of Chemical Shifts Due to the Magnetic Anisotropy of Quadruple Bonds

The monoanion of 2,6-bis(phenylamino)pyridine (HBPAP-) has been found to support quadruply bonded Cr2 4+ and Mo2 4+ units in Cr2(HBPAP)4 (1) and Mo2(HBPAP)4 (2). The corresponding dianion BPAP2- was able to stabilize the trinuclear complexes, (TBA)2Cr3(BPAP)4 (3) and (TBA)2Ni3(BPAP)4 (4), where TBA...

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Veröffentlicht in:	Inorganic chemistry 2001-06, Vol.40 (12), p.2778-2784
Hauptverfasser:	Cotton, F. Albert, Daniels, Lee M, Lei, Peng, Murillo, Carlos A, Wang, Xiaoping
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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