Orientation of benzene in supersonic expansions, probed by IR-laser absorption and by molecular beam scattering

This work represents the first experimental demonstration that planar molecules tend to travel as a "frisbee" when a gaseous mixture with lighter carriers expands into a vacuum, the orientation being due to collisions. The molecule is benzene, the prototype of aromatic chemistry. The demon...

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Veröffentlicht in:	Physical review letters 2001-05, Vol.86 (22), p.5035-5038
Hauptverfasser:	Pirani, F, Cappelletti, D, Bartolomei, M, Aquilanti, V, Scotoni, M, Vescovi, M, Ascenzi, D, Bassi, D
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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