Kinetic energy release distributions in mass spectrometry

Kinetic energy releases (KERs) in unimolecular fragmentations of singly and multiply charged ions provide information concerning ion structures, reaction energetics and dynamics. This topic is reviewed covering both early and more recent developments. The subtopics discussed are as follows: (1) intr...

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Veröffentlicht in:	Journal of mass spectrometry. 2001-05, Vol.36 (5), p.459-478
Hauptverfasser:	Laskin, J., Lifshitz, C.
Format:	Artikel
Sprache:	eng
Schlagworte:	angular momentum average KER avoided crossing biomolecules center of mass frame centrifugal barrier Chemistry clusters conical intersection Coulomb explosion density of states detailed balance electrospray ionization (ESI) energy randomization Exact sciences and technology finite heat bath theory (FHBT) fullerenes kinetic energy release (KER) kinetic energy release distribution (KERD) laboratory frame mass-analyzed Ion Kinetic Energy (MIKE) matrix-assisted laser desorption/ionization (MALDI) Maxwell-Boltzmann-like distribution metastable ions momentum gap law Noncondensed benzenic compounds Organic chemistry organometallic ions PEPICO phase space theory (PST) Preparations and properties prior distribution reaction cross-section RRKM/QET surprisal the Gspann parameter
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