Biocatalysis in Ionic Liquids: Markedly Enhanced Enantioselectivity of Lipase
Lipase-catalyzed transesterifications in ionic liquids proceeded with markedly enhanced enantioselectivity. It was observed that lipases were up to 25 times more enantioselective in ionic liquids than in conventional organic solvents.
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Veröffentlicht in: | Organic letters 2001-05, Vol.3 (10), p.1507-1509 |
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creator | Kim, Kwang-Wook Song, Boyoung Choi, Min-Young Kim, Mahn-Joo |
description | Lipase-catalyzed transesterifications in ionic liquids proceeded with markedly enhanced enantioselectivity. It was observed that lipases were up to 25 times more enantioselective in ionic liquids than in conventional organic solvents. |
doi_str_mv | 10.1021/ol015824f |
format | Article |
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Lett</addtitle><description>Lipase-catalyzed transesterifications in ionic liquids proceeded with markedly enhanced enantioselectivity. It was observed that lipases were up to 25 times more enantioselective in ionic liquids than in conventional organic solvents.</description><subject>Burkholderia cepacia - enzymology</subject><subject>Candida - enzymology</subject><subject>Catalysis</subject><subject>Ions - pharmacology</subject><subject>Lipase - drug effects</subject><subject>Lipase - metabolism</subject><subject>Solvents - pharmacology</subject><subject>Stereoisomerism</subject><issn>1523-7060</issn><issn>1523-7052</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNptkDFPwzAQhS0EolAY-AMoC0gMgbMdJy4bVAUqFcEAc3SxHeGSxm2cIGVj5W_ySzBqVRamezp9907vEXJC4ZICo1euAiokS8odckAF43EGgu1udQoDcuj9HICGzWifDCjlUkrBD8jzrXUKW6x6b31k62jqaquimV11Vvvr78-v6BGbd6OrPprUb1gro4PAurXOm8qo1n7Yto9cGW6W6M0R2Sux8uZ4M4fk9W7yMn6IZ0_30_HNLEaeZW2cKgj_BQWdoGYg0tQwWQiZjWSJyJOkMEWhE80wVZxikiDnlMEoU8gV54IPyfnad9m4VWd8my-sV6aqsDau83kGcpQB8ABerEHVOO8bU-bLxi6w6XMK-W99-ba-wJ5uTLtiYfQfuekrAGdrAJXP565r6pDxH6MfXNJ2xA</recordid><startdate>20010517</startdate><enddate>20010517</enddate><creator>Kim, Kwang-Wook</creator><creator>Song, Boyoung</creator><creator>Choi, Min-Young</creator><creator>Kim, Mahn-Joo</creator><general>American Chemical Society</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20010517</creationdate><title>Biocatalysis in Ionic Liquids: Markedly Enhanced Enantioselectivity of Lipase</title><author>Kim, Kwang-Wook ; Song, Boyoung ; Choi, Min-Young ; Kim, Mahn-Joo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a377t-6c0853510d4ad20566e28b58798faa344bebbd4d2a6c31a44a3312097ca3c3353</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><topic>Burkholderia cepacia - enzymology</topic><topic>Candida - enzymology</topic><topic>Catalysis</topic><topic>Ions - pharmacology</topic><topic>Lipase - drug effects</topic><topic>Lipase - metabolism</topic><topic>Solvents - pharmacology</topic><topic>Stereoisomerism</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kim, Kwang-Wook</creatorcontrib><creatorcontrib>Song, Boyoung</creatorcontrib><creatorcontrib>Choi, Min-Young</creatorcontrib><creatorcontrib>Kim, Mahn-Joo</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Organic letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kim, Kwang-Wook</au><au>Song, Boyoung</au><au>Choi, Min-Young</au><au>Kim, Mahn-Joo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Biocatalysis in Ionic Liquids: Markedly Enhanced Enantioselectivity of Lipase</atitle><jtitle>Organic letters</jtitle><addtitle>Org. Lett</addtitle><date>2001-05-17</date><risdate>2001</risdate><volume>3</volume><issue>10</issue><spage>1507</spage><epage>1509</epage><pages>1507-1509</pages><issn>1523-7060</issn><eissn>1523-7052</eissn><abstract>Lipase-catalyzed transesterifications in ionic liquids proceeded with markedly enhanced enantioselectivity. It was observed that lipases were up to 25 times more enantioselective in ionic liquids than in conventional organic solvents.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>11388853</pmid><doi>10.1021/ol015824f</doi><tpages>3</tpages></addata></record> |
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subjects | Burkholderia cepacia - enzymology Candida - enzymology Catalysis Ions - pharmacology Lipase - drug effects Lipase - metabolism Solvents - pharmacology Stereoisomerism |
title | Biocatalysis in Ionic Liquids: Markedly Enhanced Enantioselectivity of Lipase |
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