Biomimetic approach to the oxygen evolving center: resonance Raman investigation of a manganese mu-oxo dimer in three oxidation states

A biologically relevant dinuclear manganese mono-mu-oxo complex with a bound phenolate ligand in three oxidation states, (III,III), (III,IV) and (IV,IV), was studied using resonance Raman spectroscopy. Depending upon the excitation frequency, phenolate vibrations or mu-oxo vibrations were enhanced,...

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Veröffentlicht in:	Journal of biological inorganic chemistry 2001-04, Vol.6 (4), p.430-434
Hauptverfasser:	Albela, B, Chottard, G, Girerd, J J
Format:	Artikel
Sprache:	eng
Schlagworte:	Dimerization Manganese Compounds - chemistry Molecular Mimicry Oxides - chemistry Oxygen - chemistry Photosynthetic Reaction Center Complex Proteins - chemistry Spectrum Analysis, Raman
Online-Zugang:	Volltext
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