Trigonal Planar Copper(I) Complex:  Synthesis, Structure, and Spectra of a Redox Pair of Novel Copper(II/I) Complexes of Tridentate Bis(benzimidazol-2‘-yl) Ligand Framework as Models for Electron-Transfer Copper Proteins

The copper(II) and copper(I) complexes of the chelating ligands 2,6-bis(benzimidazol-2‘-ylthiomethyl)pyridine (bbtmp) and N,N-bis(benzimidazol-2‘-ylthioethyl)methylamine (bbtma) have been isolated and characterized by electronic and EPR spectra. The molecular structures of a redox pair of Cu(II/I) c...

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Veröffentlicht in:	Inorganic chemistry 2001-05, Vol.40 (10), p.2246-2255
Hauptverfasser:	Balamurugan, Ramalingam, Palaniandavar, Mallayan, Gopalan, R. Srinivasa
Format:	Artikel
Sprache:	eng
Schlagworte:	Benzimidazoles - chemistry Copper - chemistry Crystallography, X-Ray Electron Spin Resonance Spectroscopy Ligands Magnetic Resonance Spectroscopy Metalloproteins - chemistry Models, Chemical Organometallic Compounds - chemistry Oxidation-Reduction
Online-Zugang:	Volltext
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