Fluorescent Cyclodextrin Immobilized on a Cellulose Membrane as a Chemosensor System for Detecting Molecules
Dansyl glutamate-modified cyclodextrin (DnsGlu-β-CD) was prepared as a fluorescent host, which is capable of being immobilized on a cellulose membrane (DnsGlu-β-CD-membrane). The fluorescence intensity of DnsGlu-β-CD decreased with increasing concentration of guest molecules, indicating that the hos...
Gespeichert in:
| Veröffentlicht in: | Analytical chemistry (Washington) 2001-04, Vol.73 (8), p.1877-1880 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1880 |
|---|---|
| container_issue | 8 |
| container_start_page | 1877 |
| container_title | Analytical chemistry (Washington) |
| container_volume | 73 |
| creator | Tanabe, Tetsuya Touma, Kazuhiro Hamasaki, Keita Ueno, Akihiko |
| description | Dansyl glutamate-modified cyclodextrin (DnsGlu-β-CD) was prepared as a fluorescent host, which is capable of being immobilized on a cellulose membrane (DnsGlu-β-CD-membrane). The fluorescence intensity of DnsGlu-β-CD decreased with increasing concentration of guest molecules, indicating that the host changes the location of the dansyl group from inside to outside the cyclodextrin cavity upon guest accommodation. Similar guest-induced decrease in the fluorescence intensity was observed for DnsGlu-β-CD immobilized to a cellulose membrane. This result demonstrates that the cellulose membrane may be used as a practical supporting material of various chromophore-modified cyclodextrins and that DnsGlu-β-CD-membrane is useful as a novel disposable chemosensor for molecules. |
| doi_str_mv | 10.1021/ac001062a |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_70813564</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>72027579</sourcerecordid><originalsourceid>FETCH-LOGICAL-a470t-4e093fe98a61c08840bd3aa0f3ad2189b3ab059d7d80e1541467c36dd2e0b43d3</originalsourceid><addsrcrecordid>eNpl0FFrFDEQB_Agij2rD34BCYqCD6uTZDebfZTT2kKPKnf2NWSTWd2a3dRkF3r99KbccYX2KWHmxzDzJ-Q1g08MOPtsLAADyc0TsmAVh0IqxZ-SBQCIgtcAR-RFSlcZMWDyOTliTAgloVoQf-LnEDFZHCe63FofHN5MsR_p2TCEtvf9LToaRmroEr2ffUhIVzi00YxITbqr_8EhV8cUIl1v04QD7fL3K05op378TVfBo509ppfkWWd8wlf795j8Ovm2WZ4W5xffz5ZfzgtT1jAVJUIjOmyUkcyCUiW0ThgDnTCOM9W0wrRQNa52CpBVJStlbYV0jiO0pXDimHzYzb2O4d-MadJDny_0Pu8c5qRrUExUsszw7QN4FeY45t00Z7VSDa94Rh93yMaQUsROX8d-MHGrGei7_PUh_2zf7AfO7YDuXu4Dz-DdHphkje9yjLZPB9dIUVUsq2Kn-hznzaFr4l8ta1FXevNjrVfrn5cbeXqpZfbvd97YdH_C4_X-A0Nrp4s</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>217889252</pqid></control><display><type>article</type><title>Fluorescent Cyclodextrin Immobilized on a Cellulose Membrane as a Chemosensor System for Detecting Molecules</title><source>ACS Publications</source><creator>Tanabe, Tetsuya ; Touma, Kazuhiro ; Hamasaki, Keita ; Ueno, Akihiko</creator><creatorcontrib>Tanabe, Tetsuya ; Touma, Kazuhiro ; Hamasaki, Keita ; Ueno, Akihiko</creatorcontrib><description>Dansyl glutamate-modified cyclodextrin (DnsGlu-β-CD) was prepared as a fluorescent host, which is capable of being immobilized on a cellulose membrane (DnsGlu-β-CD-membrane). The fluorescence intensity of DnsGlu-β-CD decreased with increasing concentration of guest molecules, indicating that the host changes the location of the dansyl group from inside to outside the cyclodextrin cavity upon guest accommodation. Similar guest-induced decrease in the fluorescence intensity was observed for DnsGlu-β-CD immobilized to a cellulose membrane. This result demonstrates that the cellulose membrane may be used as a practical supporting material of various chromophore-modified cyclodextrins and that DnsGlu-β-CD-membrane is useful as a novel disposable chemosensor for molecules.</description><identifier>ISSN: 0003-2700</identifier><identifier>EISSN: 1520-6882</identifier><identifier>DOI: 10.1021/ac001062a</identifier><identifier>PMID: 11338605</identifier><identifier>CODEN: ANCHAM</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Analytical chemistry ; Cellular biology ; Chemistry ; Exact sciences and technology ; General, instrumentation ; Membranes ; Molecules</subject><ispartof>Analytical chemistry (Washington), 2001-04, Vol.73 (8), p.1877-1880</ispartof><rights>Copyright © 2001 American Chemical Society</rights><rights>2001 INIST-CNRS</rights><rights>Copyright American Chemical Society Apr 15, 2001</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a470t-4e093fe98a61c08840bd3aa0f3ad2189b3ab059d7d80e1541467c36dd2e0b43d3</citedby><cites>FETCH-LOGICAL-a470t-4e093fe98a61c08840bd3aa0f3ad2189b3ab059d7d80e1541467c36dd2e0b43d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ac001062a$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ac001062a$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,777,781,2752,27057,27905,27906,56719,56769</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=963551$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/11338605$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Tanabe, Tetsuya</creatorcontrib><creatorcontrib>Touma, Kazuhiro</creatorcontrib><creatorcontrib>Hamasaki, Keita</creatorcontrib><creatorcontrib>Ueno, Akihiko</creatorcontrib><title>Fluorescent Cyclodextrin Immobilized on a Cellulose Membrane as a Chemosensor System for Detecting Molecules</title><title>Analytical chemistry (Washington)</title><addtitle>Anal. Chem</addtitle><description>Dansyl glutamate-modified cyclodextrin (DnsGlu-β-CD) was prepared as a fluorescent host, which is capable of being immobilized on a cellulose membrane (DnsGlu-β-CD-membrane). The fluorescence intensity of DnsGlu-β-CD decreased with increasing concentration of guest molecules, indicating that the host changes the location of the dansyl group from inside to outside the cyclodextrin cavity upon guest accommodation. Similar guest-induced decrease in the fluorescence intensity was observed for DnsGlu-β-CD immobilized to a cellulose membrane. This result demonstrates that the cellulose membrane may be used as a practical supporting material of various chromophore-modified cyclodextrins and that DnsGlu-β-CD-membrane is useful as a novel disposable chemosensor for molecules.</description><subject>Analytical chemistry</subject><subject>Cellular biology</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>General, instrumentation</subject><subject>Membranes</subject><subject>Molecules</subject><issn>0003-2700</issn><issn>1520-6882</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><recordid>eNpl0FFrFDEQB_Agij2rD34BCYqCD6uTZDebfZTT2kKPKnf2NWSTWd2a3dRkF3r99KbccYX2KWHmxzDzJ-Q1g08MOPtsLAADyc0TsmAVh0IqxZ-SBQCIgtcAR-RFSlcZMWDyOTliTAgloVoQf-LnEDFZHCe63FofHN5MsR_p2TCEtvf9LToaRmroEr2ffUhIVzi00YxITbqr_8EhV8cUIl1v04QD7fL3K05op378TVfBo509ppfkWWd8wlf795j8Ovm2WZ4W5xffz5ZfzgtT1jAVJUIjOmyUkcyCUiW0ThgDnTCOM9W0wrRQNa52CpBVJStlbYV0jiO0pXDimHzYzb2O4d-MadJDny_0Pu8c5qRrUExUsszw7QN4FeY45t00Z7VSDa94Rh93yMaQUsROX8d-MHGrGei7_PUh_2zf7AfO7YDuXu4Dz-DdHphkje9yjLZPB9dIUVUsq2Kn-hznzaFr4l8ta1FXevNjrVfrn5cbeXqpZfbvd97YdH_C4_X-A0Nrp4s</recordid><startdate>20010415</startdate><enddate>20010415</enddate><creator>Tanabe, Tetsuya</creator><creator>Touma, Kazuhiro</creator><creator>Hamasaki, Keita</creator><creator>Ueno, Akihiko</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7TA</scope><scope>7TB</scope><scope>7TM</scope><scope>7U5</scope><scope>7U7</scope><scope>7U9</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>H94</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope><scope>7X8</scope></search><sort><creationdate>20010415</creationdate><title>Fluorescent Cyclodextrin Immobilized on a Cellulose Membrane as a Chemosensor System for Detecting Molecules</title><author>Tanabe, Tetsuya ; Touma, Kazuhiro ; Hamasaki, Keita ; Ueno, Akihiko</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a470t-4e093fe98a61c08840bd3aa0f3ad2189b3ab059d7d80e1541467c36dd2e0b43d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><topic>Analytical chemistry</topic><topic>Cellular biology</topic><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>General, instrumentation</topic><topic>Membranes</topic><topic>Molecules</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tanabe, Tetsuya</creatorcontrib><creatorcontrib>Touma, Kazuhiro</creatorcontrib><creatorcontrib>Hamasaki, Keita</creatorcontrib><creatorcontrib>Ueno, Akihiko</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Nucleic Acids Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Virology and AIDS Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>AIDS and Cancer Research Abstracts</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Analytical chemistry (Washington)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tanabe, Tetsuya</au><au>Touma, Kazuhiro</au><au>Hamasaki, Keita</au><au>Ueno, Akihiko</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fluorescent Cyclodextrin Immobilized on a Cellulose Membrane as a Chemosensor System for Detecting Molecules</atitle><jtitle>Analytical chemistry (Washington)</jtitle><addtitle>Anal. Chem</addtitle><date>2001-04-15</date><risdate>2001</risdate><volume>73</volume><issue>8</issue><spage>1877</spage><epage>1880</epage><pages>1877-1880</pages><issn>0003-2700</issn><eissn>1520-6882</eissn><coden>ANCHAM</coden><abstract>Dansyl glutamate-modified cyclodextrin (DnsGlu-β-CD) was prepared as a fluorescent host, which is capable of being immobilized on a cellulose membrane (DnsGlu-β-CD-membrane). The fluorescence intensity of DnsGlu-β-CD decreased with increasing concentration of guest molecules, indicating that the host changes the location of the dansyl group from inside to outside the cyclodextrin cavity upon guest accommodation. Similar guest-induced decrease in the fluorescence intensity was observed for DnsGlu-β-CD immobilized to a cellulose membrane. This result demonstrates that the cellulose membrane may be used as a practical supporting material of various chromophore-modified cyclodextrins and that DnsGlu-β-CD-membrane is useful as a novel disposable chemosensor for molecules.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>11338605</pmid><doi>10.1021/ac001062a</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0003-2700 |
| ispartof | Analytical chemistry (Washington), 2001-04, Vol.73 (8), p.1877-1880 |
| issn | 0003-2700 1520-6882 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_70813564 |
| source | ACS Publications |
| subjects | Analytical chemistry Cellular biology Chemistry Exact sciences and technology General, instrumentation Membranes Molecules |
| title | Fluorescent Cyclodextrin Immobilized on a Cellulose Membrane as a Chemosensor System for Detecting Molecules |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-20T01%3A04%3A31IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Fluorescent%20Cyclodextrin%20Immobilized%20on%20a%20Cellulose%20Membrane%20as%20a%20Chemosensor%20System%20for%20Detecting%20Molecules&rft.jtitle=Analytical%20chemistry%20(Washington)&rft.au=Tanabe,%20Tetsuya&rft.date=2001-04-15&rft.volume=73&rft.issue=8&rft.spage=1877&rft.epage=1880&rft.pages=1877-1880&rft.issn=0003-2700&rft.eissn=1520-6882&rft.coden=ANCHAM&rft_id=info:doi/10.1021/ac001062a&rft_dat=%3Cproquest_cross%3E72027579%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=217889252&rft_id=info:pmid/11338605&rfr_iscdi=true |