Methanolysis of tetraphenylborate (BPh4(-)) as a reaction unit in halotris(2,4-pentadianato) complexes of Zr(IV) and Hf(IV)

The complexes {(C5H8O2)2Zr[(OCH3)2B(C6H5)2]2.1/2C12H10} (M = Zr (1) or Hf (2)) have been obtained from the reaction of [M(acac)3Cl] with sodium tetraphenylborate (BPh4(-)) in methanol. Crystal structures show 8-coordinate complexes with two 2,4-pentanedionato groups and two dimethoxydiphenylborate g...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2008-06 (21), p.2456-2458
Hauptverfasser:	Mlondo, Sibusiso N, O'Brien, Paul, Thomas, P John, Helliwell, Madeleine, Raftery, James, Procter, David J
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystallography, X-Ray Hafnium - chemistry Methanol - chemistry Models, Molecular Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Tetraphenylborate - chemistry Zirconium - chemistry
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creator	Mlondo, Sibusiso N O'Brien, Paul Thomas, P John Helliwell, Madeleine Raftery, James Procter, David J
description	The complexes {(C5H8O2)2Zr[(OCH3)2B(C6H5)2]2.1/2C12H10} (M = Zr (1) or Hf (2)) have been obtained from the reaction of [M(acac)3Cl] with sodium tetraphenylborate (BPh4(-)) in methanol. Crystal structures show 8-coordinate complexes with two 2,4-pentanedionato groups and two dimethoxydiphenylborate groups each coordinated through methoxy groups to the metal centre.
doi_str_mv	10.1039/b800791h
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subjects	Crystallography, X-Ray Hafnium - chemistry Methanol - chemistry Models, Molecular Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Tetraphenylborate - chemistry Zirconium - chemistry
title	Methanolysis of tetraphenylborate (BPh4(-)) as a reaction unit in halotris(2,4-pentadianato) complexes of Zr(IV) and Hf(IV)
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