Site-Selective Guest Inclusion in Molecular Networks of Butadiyne-Bridged Pyridino and Benzeno Square Macrocycles on a Surface

Site-Selective Guest Inclusion in Molecular Networks of Butadiyne-Bridged Pyridino and Benzeno Square Macrocycles on a Surface

We present here the formation of a modular 2D molecular network composed of two different types of square-shaped butadiyne-bridged macrocycles, having intrinsic molecular voids, aligned alternately at the solid–liquid interface. Site-selective inclusion of a guest cation took place at every other mo...

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Veröffentlicht in:Journal of the American Chemical Society 2008-05, Vol.130 (21), p.6666-6667
Hauptverfasser: Tahara, Kazukuni, Lei, Shengbin, Mamdouh, Wael, Yamaguchi, Yui, Ichikawa, Tomoyuki, Uji-i, Hiroshi, Sonoda, Motohiro, Hirose, Keiji, De Schryver, Frans C, De Feyter, Steven, Tobe, Yoshito
Format: Artikel
Sprache:eng
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Zusammenfassung:We present here the formation of a modular 2D molecular network composed of two different types of square-shaped butadiyne-bridged macrocycles, having intrinsic molecular voids, aligned alternately at the solid–liquid interface. Site-selective inclusion of a guest cation took place at every other molecular void in the molecular network with two different recognition sites.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja711422h