Toluene-Sandwiched Trinuclear Copper(I) and Silver(I) Triazolates and Phosphine Adducts of Dinuclear Copper(I) and Silver(I) Triazolates

CuI and AgI complexes of the fluorinated triazolate ligand [3,5-(C3F7)2Tz]− have been synthesized using the corresponding metal(I) oxides and the triazole. They form π-acid/base adducts with toluene, leading to [Tol][M3][Tol] ([Tol] = toluene; [M3] = {[3,5-(C3F7)2Tz]Cu}3 or {[3,5-(C3F7)2Tz]Ag}3) typ...

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Veröffentlicht in:	Inorganic chemistry 2008-05, Vol.47 (10), p.3943-3945
Hauptverfasser:	Dias, H. V. Rasika, Singh, Shreeyukta, Campana, Charles F
Format:	Artikel
Sprache:	eng
Schlagworte:	Adducts Boats Contact Ligands Oxides Phosphines Toluene Triazoles
Online-Zugang:	Volltext
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