Construction of Electrocatalytic Electrodes Bearing the Triphenylamine Nucleus Covalently Bound to Carbon. A Halogen Dance in Protonated Aminotriphenylamines

Construction of Electrocatalytic Electrodes Bearing the Triphenylamine Nucleus Covalently Bound to Carbon. A Halogen Dance in Protonated Aminotriphenylamines

The triarylamine nucleus has been attached to a carbon fiber electrode by diazotization of an aminotriphenylamine followed by electrochemical reduction. The resulting electrodes can electrocatalyze the oxidation of organic substrates. In acid, 4-amino-4‘,4‘ ‘-dibromotriphenylamine undergoes dismutat...

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Veröffentlicht in:Organic letters 2006-02, Vol.8 (3), p.411-414
Hauptverfasser: Mayers, Brian T, Fry, Albert J
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Fry, Albert J
description The triarylamine nucleus has been attached to a carbon fiber electrode by diazotization of an aminotriphenylamine followed by electrochemical reduction. The resulting electrodes can electrocatalyze the oxidation of organic substrates. In acid, 4-amino-4‘,4‘ ‘-dibromotriphenylamine undergoes dismutation into a mixture of amines containing from 0 to 3 bromine atoms.
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title Construction of Electrocatalytic Electrodes Bearing the Triphenylamine Nucleus Covalently Bound to Carbon. A Halogen Dance in Protonated Aminotriphenylamines
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