Direct Carbon-Carbon Bond Formation from Alcohols and Active Methylenes, Alkoxyketones, or Indoles Catalyzed by Indium Trichloride

The unsalted variety: The direct coupling reaction of alcohols with active methylenes, alkoxyketones, or indoles catalyzed by InCl3 proceeds without the formation of metal salts (see scheme). As H2O is the only by‐product of this system, the alkylated products are easily isolated in pure form, and t...

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Veröffentlicht in:	Angewandte Chemie International Edition 2006-01, Vol.45 (5), p.793-796
Hauptverfasser:	Yasuda, Makoto, Somyo, Toshio, Baba, Akio
Format:	Artikel
Sprache:	eng
Schlagworte:	alcohols Alcohols - chemistry Carbon - chemistry Catalysis CC coupling indium Indium - chemistry Indoles - chemistry Ketones - chemical synthesis Ketones - chemistry Molecular Structure Stereoisomerism synthetic methods
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creator	Yasuda, Makoto Somyo, Toshio Baba, Akio
description	The unsalted variety: The direct coupling reaction of alcohols with active methylenes, alkoxyketones, or indoles catalyzed by InCl3 proceeds without the formation of metal salts (see scheme). As H2O is the only by‐product of this system, the alkylated products are easily isolated in pure form, and the reaction is suitable for large‐scale synthesis.
doi_str_mv	10.1002/anie.200503263
format	Article
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subjects	alcohols Alcohols - chemistry Carbon - chemistry Catalysis CC coupling indium Indium - chemistry Indoles - chemistry Ketones - chemical synthesis Ketones - chemistry Molecular Structure Stereoisomerism synthetic methods
title	Direct Carbon-Carbon Bond Formation from Alcohols and Active Methylenes, Alkoxyketones, or Indoles Catalyzed by Indium Trichloride
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