Copper(I) complex O(2)-reactivity with a N(3)S thioether ligand: a copper-dioxygen adduct including sulfur ligation, ligand oxygenation, and comparisons with all nitrogen ligand analogues

In order to contribute to an understanding of the effects of thioether sulfur ligation in copper-O(2) reactivity, the tetradentate ligands L(N3S) (2-ethylthio-N,N-bis(pyridin-2-yl)methylethanamine) and L(N3S')(2-ethylthio-N,N-bis(pyridin-2-yl)ethylethanamine) have been synthesized. Correspondin...

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Veröffentlicht in:	Inorganic chemistry 2007-07, Vol.46 (15), p.6056-6068
Hauptverfasser:	Lee, Dong-Heon, Hatcher, Lanying Q, Vance, Michael A, Sarangi, Ritimukta, Milligan, Ashley E, Sarjeant, Amy A Narducci, Incarvito, Christopher D, Rheingold, Arnold L, Hodgson, Keith O, Hedman, Britt, Solomon, Edward I, Karlin, Kenneth D
Format:	Artikel
Sprache:	eng
Schlagworte:	Binding Sites Copper - chemistry Crystallography, X-Ray Dimerization Ligands Methionine - chemistry Models, Chemical Models, Molecular Molecular Conformation Nitrogen - chemistry Oxygen - chemistry Spectrophotometry - methods Sulfides - chemistry Sulfur - chemistry Ultraviolet Rays
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