Indium(III) Trifluoromethanesulfonate as an Efficient Catalyst for the Deprotection of Acetals and Ketals
Acetals and ketals are readily deprotected under neutral conditions in the presence of acetone and catalytic amounts of indium(III) trifluoromethanesulfonate (
Gespeichert in:
| Veröffentlicht in: | Journal of organic chemistry 2007-07, Vol.72 (15), p.5890-5893 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 5893 |
|---|---|
| container_issue | 15 |
| container_start_page | 5890 |
| container_title | Journal of organic chemistry |
| container_volume | 72 |
| creator | Gregg, Brian T Golden, Kathryn C Quinn, John F |
| description | Acetals and ketals are readily deprotected under neutral conditions in the presence of acetone and catalytic amounts of indium(III) trifluoromethanesulfonate ( |
| doi_str_mv | 10.1021/jo0707075 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_70706556</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>70706556</sourcerecordid><originalsourceid>FETCH-LOGICAL-a381t-2e4eda8296be68845ceb904447aa440f7fda170248cdb3b00d702cbb6fb398dd3</originalsourceid><addsrcrecordid>eNptkE9PHSEUxYmx0Vfrol_AsLGpi7EwwPxZ2qfVsSZt0mfSHWHgEtGZQYFJ6rcvr-_Ft-llcSH3x8m5B6GPlJxTUtIvj57U6yP20IKKkhRVS_g-WhBSlgUrK3aI3sf4SHIJIQ7QIa1FKyhrF8h1k3Hz-LnrujO8Cs4Osw9-hPSgJojzYP2kEmAVsZrwlbVOO5gSXqqkhteYsPUBpwfAl_AcfAKdnJ-wt_hCQybWvwz-_u_6Ab2zucHxth-h-29Xq-VNcffjulte3BWKNTQVJXAwqinbqoeqabjQ0OdtOK-V4pzY2hpFa1LyRpue9YSY_NB9X9metY0x7Ah92uhmQy8zxCRHFzUMQ17Iz1Guk6qEqDJ4tgF18DEGsPI5uFGFV0mJXOcq33LN7MlWdO5HMDtyG2QGTreAiloNNqhJu7jjmpYLQurMFRvOxQR_3uYqPMmqZrWQq5-_JL-kt8uvv5mkO12lY_Yzhyln9x-DfwFBDJrQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>70706556</pqid></control><display><type>article</type><title>Indium(III) Trifluoromethanesulfonate as an Efficient Catalyst for the Deprotection of Acetals and Ketals</title><source>ACS Publications</source><source>MEDLINE</source><creator>Gregg, Brian T ; Golden, Kathryn C ; Quinn, John F</creator><creatorcontrib>Gregg, Brian T ; Golden, Kathryn C ; Quinn, John F</creatorcontrib><description>Acetals and ketals are readily deprotected under neutral conditions in the presence of acetone and catalytic amounts of indium(III) trifluoromethanesulfonate (<0.8 mol %) at room temperature or mild microwave heating conditions to give the corresponding aldehydes and ketones in good to excellent yields.</description><identifier>ISSN: 0022-3263</identifier><identifier>EISSN: 1520-6904</identifier><identifier>DOI: 10.1021/jo0707075</identifier><identifier>PMID: 17595139</identifier><identifier>CODEN: JOCEAH</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Acetals - chemistry ; Catalysis ; Catalysts: preparations and properties ; Chemistry ; Exact sciences and technology ; General and physical chemistry ; Magnetic Resonance Spectroscopy ; Organic chemistry ; Organometallic Compounds - chemistry ; Spectrometry, Mass, Electrospray Ionization ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><ispartof>Journal of organic chemistry, 2007-07, Vol.72 (15), p.5890-5893</ispartof><rights>Copyright © 2007 American Chemical Society</rights><rights>2008 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a381t-2e4eda8296be68845ceb904447aa440f7fda170248cdb3b00d702cbb6fb398dd3</citedby><cites>FETCH-LOGICAL-a381t-2e4eda8296be68845ceb904447aa440f7fda170248cdb3b00d702cbb6fb398dd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/jo0707075$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/jo0707075$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=18945007$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/17595139$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Gregg, Brian T</creatorcontrib><creatorcontrib>Golden, Kathryn C</creatorcontrib><creatorcontrib>Quinn, John F</creatorcontrib><title>Indium(III) Trifluoromethanesulfonate as an Efficient Catalyst for the Deprotection of Acetals and Ketals</title><title>Journal of organic chemistry</title><addtitle>J. Org. Chem</addtitle><description>Acetals and ketals are readily deprotected under neutral conditions in the presence of acetone and catalytic amounts of indium(III) trifluoromethanesulfonate (<0.8 mol %) at room temperature or mild microwave heating conditions to give the corresponding aldehydes and ketones in good to excellent yields.</description><subject>Acetals - chemistry</subject><subject>Catalysis</subject><subject>Catalysts: preparations and properties</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Magnetic Resonance Spectroscopy</subject><subject>Organic chemistry</subject><subject>Organometallic Compounds - chemistry</subject><subject>Spectrometry, Mass, Electrospray Ionization</subject><subject>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><issn>0022-3263</issn><issn>1520-6904</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNptkE9PHSEUxYmx0Vfrol_AsLGpi7EwwPxZ2qfVsSZt0mfSHWHgEtGZQYFJ6rcvr-_Ft-llcSH3x8m5B6GPlJxTUtIvj57U6yP20IKKkhRVS_g-WhBSlgUrK3aI3sf4SHIJIQ7QIa1FKyhrF8h1k3Hz-LnrujO8Cs4Osw9-hPSgJojzYP2kEmAVsZrwlbVOO5gSXqqkhteYsPUBpwfAl_AcfAKdnJ-wt_hCQybWvwz-_u_6Ab2zucHxth-h-29Xq-VNcffjulte3BWKNTQVJXAwqinbqoeqabjQ0OdtOK-V4pzY2hpFa1LyRpue9YSY_NB9X9metY0x7Ah92uhmQy8zxCRHFzUMQ17Iz1Guk6qEqDJ4tgF18DEGsPI5uFGFV0mJXOcq33LN7MlWdO5HMDtyG2QGTreAiloNNqhJu7jjmpYLQurMFRvOxQR_3uYqPMmqZrWQq5-_JL-kt8uvv5mkO12lY_Yzhyln9x-DfwFBDJrQ</recordid><startdate>20070720</startdate><enddate>20070720</enddate><creator>Gregg, Brian T</creator><creator>Golden, Kathryn C</creator><creator>Quinn, John F</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20070720</creationdate><title>Indium(III) Trifluoromethanesulfonate as an Efficient Catalyst for the Deprotection of Acetals and Ketals</title><author>Gregg, Brian T ; Golden, Kathryn C ; Quinn, John F</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a381t-2e4eda8296be68845ceb904447aa440f7fda170248cdb3b00d702cbb6fb398dd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Acetals - chemistry</topic><topic>Catalysis</topic><topic>Catalysts: preparations and properties</topic><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Magnetic Resonance Spectroscopy</topic><topic>Organic chemistry</topic><topic>Organometallic Compounds - chemistry</topic><topic>Spectrometry, Mass, Electrospray Ionization</topic><topic>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gregg, Brian T</creatorcontrib><creatorcontrib>Golden, Kathryn C</creatorcontrib><creatorcontrib>Quinn, John F</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of organic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gregg, Brian T</au><au>Golden, Kathryn C</au><au>Quinn, John F</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Indium(III) Trifluoromethanesulfonate as an Efficient Catalyst for the Deprotection of Acetals and Ketals</atitle><jtitle>Journal of organic chemistry</jtitle><addtitle>J. Org. Chem</addtitle><date>2007-07-20</date><risdate>2007</risdate><volume>72</volume><issue>15</issue><spage>5890</spage><epage>5893</epage><pages>5890-5893</pages><issn>0022-3263</issn><eissn>1520-6904</eissn><coden>JOCEAH</coden><abstract>Acetals and ketals are readily deprotected under neutral conditions in the presence of acetone and catalytic amounts of indium(III) trifluoromethanesulfonate (<0.8 mol %) at room temperature or mild microwave heating conditions to give the corresponding aldehydes and ketones in good to excellent yields.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>17595139</pmid><doi>10.1021/jo0707075</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-3263 |
| ispartof | Journal of organic chemistry, 2007-07, Vol.72 (15), p.5890-5893 |
| issn | 0022-3263 1520-6904 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_70706556 |
| source | ACS Publications; MEDLINE |
| subjects | Acetals - chemistry Catalysis Catalysts: preparations and properties Chemistry Exact sciences and technology General and physical chemistry Magnetic Resonance Spectroscopy Organic chemistry Organometallic Compounds - chemistry Spectrometry, Mass, Electrospray Ionization Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
| title | Indium(III) Trifluoromethanesulfonate as an Efficient Catalyst for the Deprotection of Acetals and Ketals |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-10T14%3A18%3A27IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Indium(III)%20Trifluoromethanesulfonate%20as%20an%20Efficient%20Catalyst%20for%20the%20Deprotection%20of%20Acetals%20and%20Ketals&rft.jtitle=Journal%20of%20organic%20chemistry&rft.au=Gregg,%20Brian%20T&rft.date=2007-07-20&rft.volume=72&rft.issue=15&rft.spage=5890&rft.epage=5893&rft.pages=5890-5893&rft.issn=0022-3263&rft.eissn=1520-6904&rft.coden=JOCEAH&rft_id=info:doi/10.1021/jo0707075&rft_dat=%3Cproquest_cross%3E70706556%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=70706556&rft_id=info:pmid/17595139&rfr_iscdi=true |