Development, Mechanism, and Scope of the Palladium-Catalyzed Enantioselective Allene Diboration

In the presence of a chiral phosphoramidite ligand, the palladium-catalyzed diboration of allenes can be executed with high enantioselectivity. This reaction provides high levels of selectivity with a range of aromatic and aliphatic allene substrates. Isotopic-labeling experiments, stereodifferentia...

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Veröffentlicht in:	Journal of the American Chemical Society 2007-07, Vol.129 (28), p.8766-8773
Hauptverfasser:	Burks, Heather E, Liu, Shubin, Morken, James P
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkadienes - chemistry Boron - chemistry Boron Compounds - chemical synthesis Catalysis Hydrocarbons, Aromatic - chemistry Organic Chemicals - chemical synthesis Palladium
Online-Zugang:	Volltext
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