Fine Size Control of Platinum on Carbon Nanotubes: From Single Atoms to Clusters

Bond formation between single Pt atoms and surface thiol groups is the result of the reduction of a Pt precursor in the presence of surface‐thiolated carbon nanotubes. By setting the temperature of the following heat treatment, finely size‐controlled and monodispersed Pt clusters were obtained from...

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Veröffentlicht in:Angewandte Chemie International Edition 2006-01, Vol.45 (3), p.407-411
Hauptverfasser: Kim, Yong-Tae, Ohshima, Kazuyoshi, Higashimine, Koichi, Uruga, Tomoya, Takata, Masaki, Suematsu, Hiroyoshi, Mitani, Tadaoki
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container_issue 3
container_start_page 407
container_title Angewandte Chemie International Edition
container_volume 45
creator Kim, Yong-Tae
Ohshima, Kazuyoshi
Higashimine, Koichi
Uruga, Tomoya
Takata, Masaki
Suematsu, Hiroyoshi
Mitani, Tadaoki
description Bond formation between single Pt atoms and surface thiol groups is the result of the reduction of a Pt precursor in the presence of surface‐thiolated carbon nanotubes. By setting the temperature of the following heat treatment, finely size‐controlled and monodispersed Pt clusters were obtained from the dispersed single atoms (see picture).
doi_str_mv 10.1002/anie.200501792
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subjects carbon
electrocatalysts
electrochemistry
nanotubes
Nanotubes, Carbon - chemistry
Particle Size
platinum
Platinum - chemistry
Powder Diffraction - methods
Sensitivity and Specificity
Spectrometry, X-Ray Emission - methods
Surface Properties
Temperature
title Fine Size Control of Platinum on Carbon Nanotubes: From Single Atoms to Clusters
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