Distinction of Absolute Configuration at C-22 of C-23-Hydroxyspirostane and C-23-Hydroxyspirosolane Glycosides
It has been revealed that the absolute configurations at C-22 of 23-hydroxyspirostane and 23-hydroxyspirosolane could be unambiguouly judged by the 1H- and 13C-NMR spectroscopies.
Gespeichert in:
Veröffentlicht in: | Chemical & Pharmaceutical Bulletin 2007, Vol.55(7), pp.1079-1081 |
---|---|
Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 1081 |
---|---|
container_issue | 7 |
container_start_page | 1079 |
container_title | Chemical & Pharmaceutical Bulletin |
container_volume | 55 |
creator | Matsushita, Sayaka Yanai, Yoshihiro Fusyuku, Asami Ikeda, Tsuyoshi Ono, Masateru Nohara, Toshihiro |
description | It has been revealed that the absolute configurations at C-22 of 23-hydroxyspirostane and 23-hydroxyspirosolane could be unambiguouly judged by the 1H- and 13C-NMR spectroscopies. |
doi_str_mv | 10.1248/cpb.55.1079 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_70661232</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3133612841</sourcerecordid><originalsourceid>FETCH-LOGICAL-c5139-6b296deb0ffac9c68a8832c8e937a7ee3a9fc08a885680caffdc229fc71076603</originalsourceid><addsrcrecordid>eNptkUtr3DAUhUVJaSZpV90XQ6Cb4OmVNHp41zDNoxDopl0LWZYSDR5pKtmQ-feR40kCIRtduOfTuS-EvmJYYrKSP8yuXTK2xCCaD2iB6UrUjBB6hBYA0NSEcnqMTnLeABAGgn5Cx1hwoATEAoVfPg8-mMHHUEVXXbQ59uNgq3UMzt-NST8peqjWNSETUSKtb_Zdig_7vPMp5kEHW-nQvSPFftKu-72J2Xc2f0Yfne6z_XKIp-jf1eXf9U19--f69_ritjYM06bmLWl4Z1twTpvGcKmlpMRI21ChhbVUN87AlGVcgtHOdYaQkhNlC7zMdoq-z767FP-PNg9q67Ox_dROHLMSwDkmlBTw7A24iWMKpTeFV8VISixooc5nypSZcrJO7ZLf6rRXGNR0BFWOoBhT0xEK_e3gObZb272yh60X4GoGiuqN7mPofbCvlU0W5t5uvSIAQgEwNgUy25dH4kbwFZ_6-jkbbcoR7uxLJZ0Gb3r73JWYn6ffL9K9TsoG-gji4a8p</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1460388173</pqid></control><display><type>article</type><title>Distinction of Absolute Configuration at C-22 of C-23-Hydroxyspirostane and C-23-Hydroxyspirosolane Glycosides</title><source>J-STAGE Free</source><source>MEDLINE</source><source>EZB-FREE-00999 freely available EZB journals</source><source>Free Full-Text Journals in Chemistry</source><creator>Matsushita, Sayaka ; Yanai, Yoshihiro ; Fusyuku, Asami ; Ikeda, Tsuyoshi ; Ono, Masateru ; Nohara, Toshihiro</creator><creatorcontrib>Matsushita, Sayaka ; Yanai, Yoshihiro ; Fusyuku, Asami ; Ikeda, Tsuyoshi ; Ono, Masateru ; Nohara, Toshihiro ; aFaculty of Medical and Pharmaceutical Sciences ; Kumamoto University ; Kyushu Tokai University ; bSchool of Agriculture</creatorcontrib><description>It has been revealed that the absolute configurations at C-22 of 23-hydroxyspirostane and 23-hydroxyspirosolane could be unambiguouly judged by the 1H- and 13C-NMR spectroscopies.</description><identifier>ISSN: 0009-2363</identifier><identifier>EISSN: 1347-5223</identifier><identifier>DOI: 10.1248/cpb.55.1079</identifier><identifier>PMID: 17603207</identifier><language>eng</language><publisher>Japan: The Pharmaceutical Society of Japan</publisher><subject>23-hydroxyspirosolane ; 23-hydroxyspirostane ; C-22 absolute configuration ; Glycosides - chemistry ; Magnetic Resonance Spectroscopy ; Molecular Conformation ; Molecular Structure ; Spirostans - chemistry ; Stereoisomerism</subject><ispartof>Chemical and Pharmaceutical Bulletin, 2007, Vol.55(7), pp.1079-1081</ispartof><rights>2007 The Pharmaceutical Society of Japan</rights><rights>Copyright Japan Science and Technology Agency 2007</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5139-6b296deb0ffac9c68a8832c8e937a7ee3a9fc08a885680caffdc229fc71076603</citedby><cites>FETCH-LOGICAL-c5139-6b296deb0ffac9c68a8832c8e937a7ee3a9fc08a885680caffdc229fc71076603</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,1876,27903,27904</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/17603207$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Matsushita, Sayaka</creatorcontrib><creatorcontrib>Yanai, Yoshihiro</creatorcontrib><creatorcontrib>Fusyuku, Asami</creatorcontrib><creatorcontrib>Ikeda, Tsuyoshi</creatorcontrib><creatorcontrib>Ono, Masateru</creatorcontrib><creatorcontrib>Nohara, Toshihiro</creatorcontrib><creatorcontrib>aFaculty of Medical and Pharmaceutical Sciences</creatorcontrib><creatorcontrib>Kumamoto University</creatorcontrib><creatorcontrib>Kyushu Tokai University</creatorcontrib><creatorcontrib>bSchool of Agriculture</creatorcontrib><title>Distinction of Absolute Configuration at C-22 of C-23-Hydroxyspirostane and C-23-Hydroxyspirosolane Glycosides</title><title>Chemical & Pharmaceutical Bulletin</title><addtitle>Chem. Pharm. Bull.</addtitle><description>It has been revealed that the absolute configurations at C-22 of 23-hydroxyspirostane and 23-hydroxyspirosolane could be unambiguouly judged by the 1H- and 13C-NMR spectroscopies.</description><subject>23-hydroxyspirosolane</subject><subject>23-hydroxyspirostane</subject><subject>C-22 absolute configuration</subject><subject>Glycosides - chemistry</subject><subject>Magnetic Resonance Spectroscopy</subject><subject>Molecular Conformation</subject><subject>Molecular Structure</subject><subject>Spirostans - chemistry</subject><subject>Stereoisomerism</subject><issn>0009-2363</issn><issn>1347-5223</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNptkUtr3DAUhUVJaSZpV90XQ6Cb4OmVNHp41zDNoxDopl0LWZYSDR5pKtmQ-feR40kCIRtduOfTuS-EvmJYYrKSP8yuXTK2xCCaD2iB6UrUjBB6hBYA0NSEcnqMTnLeABAGgn5Cx1hwoATEAoVfPg8-mMHHUEVXXbQ59uNgq3UMzt-NST8peqjWNSETUSKtb_Zdig_7vPMp5kEHW-nQvSPFftKu-72J2Xc2f0Yfne6z_XKIp-jf1eXf9U19--f69_ritjYM06bmLWl4Z1twTpvGcKmlpMRI21ChhbVUN87AlGVcgtHOdYaQkhNlC7zMdoq-z767FP-PNg9q67Ox_dROHLMSwDkmlBTw7A24iWMKpTeFV8VISixooc5nypSZcrJO7ZLf6rRXGNR0BFWOoBhT0xEK_e3gObZb272yh60X4GoGiuqN7mPofbCvlU0W5t5uvSIAQgEwNgUy25dH4kbwFZ_6-jkbbcoR7uxLJZ0Gb3r73JWYn6ffL9K9TsoG-gji4a8p</recordid><startdate>200707</startdate><enddate>200707</enddate><creator>Matsushita, Sayaka</creator><creator>Yanai, Yoshihiro</creator><creator>Fusyuku, Asami</creator><creator>Ikeda, Tsuyoshi</creator><creator>Ono, Masateru</creator><creator>Nohara, Toshihiro</creator><general>The Pharmaceutical Society of Japan</general><general>Pharmaceutical Society of Japan</general><general>Japan Science and Technology Agency</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TK</scope><scope>7TM</scope><scope>7U9</scope><scope>H94</scope><scope>7X8</scope></search><sort><creationdate>200707</creationdate><title>Distinction of Absolute Configuration at C-22 of C-23-Hydroxyspirostane and C-23-Hydroxyspirosolane Glycosides</title><author>Matsushita, Sayaka ; Yanai, Yoshihiro ; Fusyuku, Asami ; Ikeda, Tsuyoshi ; Ono, Masateru ; Nohara, Toshihiro</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5139-6b296deb0ffac9c68a8832c8e937a7ee3a9fc08a885680caffdc229fc71076603</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>23-hydroxyspirosolane</topic><topic>23-hydroxyspirostane</topic><topic>C-22 absolute configuration</topic><topic>Glycosides - chemistry</topic><topic>Magnetic Resonance Spectroscopy</topic><topic>Molecular Conformation</topic><topic>Molecular Structure</topic><topic>Spirostans - chemistry</topic><topic>Stereoisomerism</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Matsushita, Sayaka</creatorcontrib><creatorcontrib>Yanai, Yoshihiro</creatorcontrib><creatorcontrib>Fusyuku, Asami</creatorcontrib><creatorcontrib>Ikeda, Tsuyoshi</creatorcontrib><creatorcontrib>Ono, Masateru</creatorcontrib><creatorcontrib>Nohara, Toshihiro</creatorcontrib><creatorcontrib>aFaculty of Medical and Pharmaceutical Sciences</creatorcontrib><creatorcontrib>Kumamoto University</creatorcontrib><creatorcontrib>Kyushu Tokai University</creatorcontrib><creatorcontrib>bSchool of Agriculture</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Neurosciences Abstracts</collection><collection>Nucleic Acids Abstracts</collection><collection>Virology and AIDS Abstracts</collection><collection>AIDS and Cancer Research Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical & Pharmaceutical Bulletin</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Matsushita, Sayaka</au><au>Yanai, Yoshihiro</au><au>Fusyuku, Asami</au><au>Ikeda, Tsuyoshi</au><au>Ono, Masateru</au><au>Nohara, Toshihiro</au><aucorp>aFaculty of Medical and Pharmaceutical Sciences</aucorp><aucorp>Kumamoto University</aucorp><aucorp>Kyushu Tokai University</aucorp><aucorp>bSchool of Agriculture</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Distinction of Absolute Configuration at C-22 of C-23-Hydroxyspirostane and C-23-Hydroxyspirosolane Glycosides</atitle><jtitle>Chemical & Pharmaceutical Bulletin</jtitle><addtitle>Chem. Pharm. Bull.</addtitle><date>2007-07</date><risdate>2007</risdate><volume>55</volume><issue>7</issue><spage>1079</spage><epage>1081</epage><pages>1079-1081</pages><issn>0009-2363</issn><eissn>1347-5223</eissn><abstract>It has been revealed that the absolute configurations at C-22 of 23-hydroxyspirostane and 23-hydroxyspirosolane could be unambiguouly judged by the 1H- and 13C-NMR spectroscopies.</abstract><cop>Japan</cop><pub>The Pharmaceutical Society of Japan</pub><pmid>17603207</pmid><doi>10.1248/cpb.55.1079</doi><tpages>3</tpages><oa>free_for_read</oa></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0009-2363 |
ispartof | Chemical and Pharmaceutical Bulletin, 2007, Vol.55(7), pp.1079-1081 |
issn | 0009-2363 1347-5223 |
language | eng |
recordid | cdi_proquest_miscellaneous_70661232 |
source | J-STAGE Free; MEDLINE; EZB-FREE-00999 freely available EZB journals; Free Full-Text Journals in Chemistry |
subjects | 23-hydroxyspirosolane 23-hydroxyspirostane C-22 absolute configuration Glycosides - chemistry Magnetic Resonance Spectroscopy Molecular Conformation Molecular Structure Spirostans - chemistry Stereoisomerism |
title | Distinction of Absolute Configuration at C-22 of C-23-Hydroxyspirostane and C-23-Hydroxyspirosolane Glycosides |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-22T14%3A01%3A12IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Distinction%20of%20Absolute%20Configuration%20at%20C-22%20of%20C-23-Hydroxyspirostane%20and%20C-23-Hydroxyspirosolane%20Glycosides&rft.jtitle=Chemical%20&%20Pharmaceutical%20Bulletin&rft.au=Matsushita,%20Sayaka&rft.aucorp=aFaculty%20of%20Medical%20and%20Pharmaceutical%20Sciences&rft.date=2007-07&rft.volume=55&rft.issue=7&rft.spage=1079&rft.epage=1081&rft.pages=1079-1081&rft.issn=0009-2363&rft.eissn=1347-5223&rft_id=info:doi/10.1248/cpb.55.1079&rft_dat=%3Cproquest_cross%3E3133612841%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1460388173&rft_id=info:pmid/17603207&rfr_iscdi=true |