sp carbon chains surrounded by sp(3) carbon double helices: coordination-driven self-assembly of wirelike Pt(CC)(n)Pt moieties that are spanned by two P(CH(2))(m)P linkages

Reactions of trans,trans-(C6F5)(p-tol3P)2Pt(CC)4Pt(Pp-tol3)2(C6F5) and diphosphines Ar2P(CH2)mPAr2 yield trans,trans-(C6F5)(Ar2P(CH2)mPAr2)Pt(CC)4Pt(Ar2P(CH2)mPAr2)(C6F5), in which the platinum atoms are spanned via an sp and two sp3 carbon chains (Ar/m = 3, Ph/14, 87%; 4, p-tol/14, 91%; 5, p-C6H4-t...

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Veröffentlicht in:	Journal of the American Chemical Society 2007-07, Vol.129 (26), p.8282-8295
Hauptverfasser:	Stahl, Jürgen, Mohr, Wolfgang, de Quadras, Laura, Peters, Thomas B, Bohling, James C, Martín-Alvarez, José Miguel, Owen, Gareth R, Hampel, Frank, Gladysz, John A
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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