A β-Diketiminate-Supported Boron Dication
The first example of a mononuclear boron dication has been prepared and isolated as the bis(trifluoromethanesulfonate) salt of its 2,2‘-bipyridine complex. The compound [(HC(CMe)2(NC6F5)2(bipy)B][OTf]2 (1) was prepared by treatment of the β-diketiminate-supported boron bis(trifluoromethylsulfonate)...
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| Veröffentlicht in: | Journal of the American Chemical Society 2007-07, Vol.129 (27), p.8436-8437 |
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| container_title | Journal of the American Chemical Society |
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| creator | Vidovic, Dragoslav Findlater, Michael Cowley, Alan H |
| description | The first example of a mononuclear boron dication has been prepared and isolated as the bis(trifluoromethanesulfonate) salt of its 2,2‘-bipyridine complex. The compound [(HC(CMe)2(NC6F5)2(bipy)B][OTf]2 (1) was prepared by treatment of the β-diketiminate-supported boron bis(trifluoromethylsulfonate) [(HC(CMe)2(NC6F5)2B(OTf)2] (2) with 2,2‘-bipyridine. The X-ray crystal structures of 1 and 2 were determined, and DFT calculations were performed on 1 and [(HC(CMe)2(NC6F5)2B]2+. |
| doi_str_mv | 10.1021/ja072865j |
| format | Article |
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The compound [(HC(CMe)2(NC6F5)2(bipy)B][OTf]2 (1) was prepared by treatment of the β-diketiminate-supported boron bis(trifluoromethylsulfonate) [(HC(CMe)2(NC6F5)2B(OTf)2] (2) with 2,2‘-bipyridine. 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Am. Chem. Soc</addtitle><description>The first example of a mononuclear boron dication has been prepared and isolated as the bis(trifluoromethanesulfonate) salt of its 2,2‘-bipyridine complex. The compound [(HC(CMe)2(NC6F5)2(bipy)B][OTf]2 (1) was prepared by treatment of the β-diketiminate-supported boron bis(trifluoromethylsulfonate) [(HC(CMe)2(NC6F5)2B(OTf)2] (2) with 2,2‘-bipyridine. The X-ray crystal structures of 1 and 2 were determined, and DFT calculations were performed on 1 and [(HC(CMe)2(NC6F5)2B]2+.</description><subject>Boron - chemistry</subject><subject>Crystallography, X-Ray</subject><subject>Imines - chemistry</subject><subject>Models, Molecular</subject><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNptkN9KwzAUh4Mobk4vfAHZjYJCNUmbNL2cm383UNj0Npy2KaSuTU1a0NfyQXwmIx3zxqtzDufjdw4fQscEXxJMyVUJOKaCs3IHDQmjOGCE8l00xBjTIBY8HKAD50o_RlSQfTQgMeMJi8gQXUzG31_BTL-pVle6hlYFy65pjG1VPr421tTjmc6g1aY-RHsFrJ062tQRerm9WU3vg8XT3cN0sgggZKQNcsKApwoLIkCkPAuBYMJ5koeYFjTClIYxi3IoBPieJXEKkIkcGIQ8JymEI3TW5zbWvHfKtbLSLlPrNdTKdE7GmLM4EcyD5z2YWeOcVYVsrK7AfkqC5a8YuRXj2ZNNaJdWKv8jNyY8EPSAdq362O7Bvkke-4_l6nkpo1f6OF8kczn1_GnPQ-ZkaTpbeyf_HP4BcOl3iw</recordid><startdate>20070711</startdate><enddate>20070711</enddate><creator>Vidovic, Dragoslav</creator><creator>Findlater, Michael</creator><creator>Cowley, Alan H</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20070711</creationdate><title>A β-Diketiminate-Supported Boron Dication</title><author>Vidovic, Dragoslav ; Findlater, Michael ; Cowley, Alan H</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a351t-d15a6be0818a8b6c3a101669d302f240223754daf8a022597baac8da5a36d1ba3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Boron - chemistry</topic><topic>Crystallography, X-Ray</topic><topic>Imines - chemistry</topic><topic>Models, Molecular</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Vidovic, Dragoslav</creatorcontrib><creatorcontrib>Findlater, Michael</creatorcontrib><creatorcontrib>Cowley, Alan H</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vidovic, Dragoslav</au><au>Findlater, Michael</au><au>Cowley, Alan H</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A β-Diketiminate-Supported Boron Dication</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>2007-07-11</date><risdate>2007</risdate><volume>129</volume><issue>27</issue><spage>8436</spage><epage>8437</epage><pages>8436-8437</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><abstract>The first example of a mononuclear boron dication has been prepared and isolated as the bis(trifluoromethanesulfonate) salt of its 2,2‘-bipyridine complex. The compound [(HC(CMe)2(NC6F5)2(bipy)B][OTf]2 (1) was prepared by treatment of the β-diketiminate-supported boron bis(trifluoromethylsulfonate) [(HC(CMe)2(NC6F5)2B(OTf)2] (2) with 2,2‘-bipyridine. The X-ray crystal structures of 1 and 2 were determined, and DFT calculations were performed on 1 and [(HC(CMe)2(NC6F5)2B]2+.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>17569541</pmid><doi>10.1021/ja072865j</doi><tpages>2</tpages></addata></record> |
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| subjects | Boron - chemistry Crystallography, X-Ray Imines - chemistry Models, Molecular |
| title | A β-Diketiminate-Supported Boron Dication |
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