Helical Arrangement of Interstrand Stacked Pyrenes in a DNA Framework

Getting it together: Helical self‐organization between oligopyrene strands with 14 consecutive achiral pyrene building blocks embedded in a DNA strand leads to an artificial double helix (see example, oligopyrene regions are shown in dark colors and the flanking DNA regions in light colors). Helicit...

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Veröffentlicht in:	Angewandte Chemie International Edition 2007-01, Vol.46 (24), p.4464-4467
Hauptverfasser:	Malinovskii, Vladimir L., Samain, Florent, Häner, Robert
Format:	Artikel
Sprache:	eng
Schlagworte:	DNA DNA - chemistry helical structures Molecular Conformation nanostructures Nanotechnology - methods pyrenes Pyrenes - chemistry stacking interactions
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description	Getting it together: Helical self‐organization between oligopyrene strands with 14 consecutive achiral pyrene building blocks embedded in a DNA strand leads to an artificial double helix (see example, oligopyrene regions are shown in dark colors and the flanking DNA regions in light colors). Helicity within the interstrand‐stacked oligopyrenes is evident from the observation of exciton‐coupled CD signals originating from the pyrene moieties.
doi_str_mv	10.1002/anie.200700891
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subjects	DNA DNA - chemistry helical structures Molecular Conformation nanostructures Nanotechnology - methods pyrenes Pyrenes - chemistry stacking interactions
title	Helical Arrangement of Interstrand Stacked Pyrenes in a DNA Framework
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