Electrolyte-Dependent Pairwise Particle Motion near Electrodes at Frequencies below 1 kHz
A model incorporating a phase angle between an applied electric field and the motion of particles driven by it explains electrolyte-dependent pairwise particle motion near electrodes. The model, predicting that two particles aggregate when this phase angle is greater than 90° but separate when the p...
Gespeichert in:
| Veröffentlicht in: | Langmuir 2007-06, Vol.23 (13), p.6983-6990 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 6990 |
|---|---|
| container_issue | 13 |
| container_start_page | 6983 |
| container_title | Langmuir |
| container_volume | 23 |
| creator | Hoggard, James D Sides, Paul J Prieve, Dennis C |
| description | A model incorporating a phase angle between an applied electric field and the motion of particles driven by it explains electrolyte-dependent pairwise particle motion near electrodes. The model, predicting that two particles aggregate when this phase angle is greater than 90° but separate when the phase angle is less than 90°, was based largely on contrasting behavior in two electrolytes (KOH and NaHCO3) used with indium tin oxide (ITO) electrodes. The present contribution expands the experimental evidence for this model to KOH, NaHCO3, NaOH, NH4OH, KCl, and H2CO3 solutions with Pt, as well as ITO electrodes. The phase angle correlation was verified in all cases. Comparisons of the model predictions to experimental data show that the sign and order of magnitude of rates of change in the separation distances between particle pairs are correctly predicted. |
| doi_str_mv | 10.1021/la070049j |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_70606605</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>70606605</sourcerecordid><originalsourceid>FETCH-LOGICAL-a381t-8e0a9832ac6776e3d5024d01158474916fa5e5cda07918d105a2e8e4a330ff913</originalsourceid><addsrcrecordid>eNptkE1v1DAQhi0EokvhwB9AuVCJQ2D87RxR220rFajEcuBkTZ2JlG02WWyvSvn1dbVR98LJtubxOzMPY-85fOYg-JcBwQKoZv2CLbgWUGsn7Eu2AKtkbZWRR-xNSmsAaKRqXrMjbrXgAtSC_T4fKOQ4DQ-Z6jPa0tjSmKsb7ON9n6hcYu7DQNW3KffTWI2EsZr_tJQqzNUy0p8djaEvz1sapvuKV3eX_96yVx0Oid7N5zH7tTxfnV7W1z8urk6_XtcoHc-1I8DGSYHBWGtIthqEaoFz7ZRVDTcdatKhLSs23LUcNApypFBK6LqGy2N2ss_dxqnMkbLf9CnQMOBI0y55CwaMAV3AT3swxCmlSJ3fxn6D8cFz8E8e_bPHwn6YQ3e3G2oP5CyuAB9nAFPAoYtYBKQD55zijXhqWu-5PmX6-1zHeOeNlVb71c1PL87M6vvyQnp9yMWQ_HraxbG4-8-Aj4wGlEU</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>70606605</pqid></control><display><type>article</type><title>Electrolyte-Dependent Pairwise Particle Motion near Electrodes at Frequencies below 1 kHz</title><source>MEDLINE</source><source>American Chemical Society Publications</source><creator>Hoggard, James D ; Sides, Paul J ; Prieve, Dennis C</creator><creatorcontrib>Hoggard, James D ; Sides, Paul J ; Prieve, Dennis C</creatorcontrib><description>A model incorporating a phase angle between an applied electric field and the motion of particles driven by it explains electrolyte-dependent pairwise particle motion near electrodes. The model, predicting that two particles aggregate when this phase angle is greater than 90° but separate when the phase angle is less than 90°, was based largely on contrasting behavior in two electrolytes (KOH and NaHCO3) used with indium tin oxide (ITO) electrodes. The present contribution expands the experimental evidence for this model to KOH, NaHCO3, NaOH, NH4OH, KCl, and H2CO3 solutions with Pt, as well as ITO electrodes. The phase angle correlation was verified in all cases. Comparisons of the model predictions to experimental data show that the sign and order of magnitude of rates of change in the separation distances between particle pairs are correctly predicted.</description><identifier>ISSN: 0743-7463</identifier><identifier>EISSN: 1520-5827</identifier><identifier>DOI: 10.1021/la070049j</identifier><identifier>PMID: 17521204</identifier><identifier>CODEN: LANGD5</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Chemistry ; Colloidal state and disperse state ; Colloids - chemistry ; Electrodes ; Electrolytes - chemistry ; Electromagnetic Fields ; Exact sciences and technology ; General and physical chemistry ; Models, Chemical ; Surface physical chemistry ; Tin Compounds</subject><ispartof>Langmuir, 2007-06, Vol.23 (13), p.6983-6990</ispartof><rights>Copyright © 2007 American Chemical Society</rights><rights>2007 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a381t-8e0a9832ac6776e3d5024d01158474916fa5e5cda07918d105a2e8e4a330ff913</citedby><cites>FETCH-LOGICAL-a381t-8e0a9832ac6776e3d5024d01158474916fa5e5cda07918d105a2e8e4a330ff913</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/la070049j$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/la070049j$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=18841925$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/17521204$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Hoggard, James D</creatorcontrib><creatorcontrib>Sides, Paul J</creatorcontrib><creatorcontrib>Prieve, Dennis C</creatorcontrib><title>Electrolyte-Dependent Pairwise Particle Motion near Electrodes at Frequencies below 1 kHz</title><title>Langmuir</title><addtitle>Langmuir</addtitle><description>A model incorporating a phase angle between an applied electric field and the motion of particles driven by it explains electrolyte-dependent pairwise particle motion near electrodes. The model, predicting that two particles aggregate when this phase angle is greater than 90° but separate when the phase angle is less than 90°, was based largely on contrasting behavior in two electrolytes (KOH and NaHCO3) used with indium tin oxide (ITO) electrodes. The present contribution expands the experimental evidence for this model to KOH, NaHCO3, NaOH, NH4OH, KCl, and H2CO3 solutions with Pt, as well as ITO electrodes. The phase angle correlation was verified in all cases. Comparisons of the model predictions to experimental data show that the sign and order of magnitude of rates of change in the separation distances between particle pairs are correctly predicted.</description><subject>Chemistry</subject><subject>Colloidal state and disperse state</subject><subject>Colloids - chemistry</subject><subject>Electrodes</subject><subject>Electrolytes - chemistry</subject><subject>Electromagnetic Fields</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Models, Chemical</subject><subject>Surface physical chemistry</subject><subject>Tin Compounds</subject><issn>0743-7463</issn><issn>1520-5827</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNptkE1v1DAQhi0EokvhwB9AuVCJQ2D87RxR220rFajEcuBkTZ2JlG02WWyvSvn1dbVR98LJtubxOzMPY-85fOYg-JcBwQKoZv2CLbgWUGsn7Eu2AKtkbZWRR-xNSmsAaKRqXrMjbrXgAtSC_T4fKOQ4DQ-Z6jPa0tjSmKsb7ON9n6hcYu7DQNW3KffTWI2EsZr_tJQqzNUy0p8djaEvz1sapvuKV3eX_96yVx0Oid7N5zH7tTxfnV7W1z8urk6_XtcoHc-1I8DGSYHBWGtIthqEaoFz7ZRVDTcdatKhLSs23LUcNApypFBK6LqGy2N2ss_dxqnMkbLf9CnQMOBI0y55CwaMAV3AT3swxCmlSJ3fxn6D8cFz8E8e_bPHwn6YQ3e3G2oP5CyuAB9nAFPAoYtYBKQD55zijXhqWu-5PmX6-1zHeOeNlVb71c1PL87M6vvyQnp9yMWQ_HraxbG4-8-Aj4wGlEU</recordid><startdate>20070619</startdate><enddate>20070619</enddate><creator>Hoggard, James D</creator><creator>Sides, Paul J</creator><creator>Prieve, Dennis C</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20070619</creationdate><title>Electrolyte-Dependent Pairwise Particle Motion near Electrodes at Frequencies below 1 kHz</title><author>Hoggard, James D ; Sides, Paul J ; Prieve, Dennis C</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a381t-8e0a9832ac6776e3d5024d01158474916fa5e5cda07918d105a2e8e4a330ff913</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Chemistry</topic><topic>Colloidal state and disperse state</topic><topic>Colloids - chemistry</topic><topic>Electrodes</topic><topic>Electrolytes - chemistry</topic><topic>Electromagnetic Fields</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Models, Chemical</topic><topic>Surface physical chemistry</topic><topic>Tin Compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hoggard, James D</creatorcontrib><creatorcontrib>Sides, Paul J</creatorcontrib><creatorcontrib>Prieve, Dennis C</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Langmuir</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hoggard, James D</au><au>Sides, Paul J</au><au>Prieve, Dennis C</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrolyte-Dependent Pairwise Particle Motion near Electrodes at Frequencies below 1 kHz</atitle><jtitle>Langmuir</jtitle><addtitle>Langmuir</addtitle><date>2007-06-19</date><risdate>2007</risdate><volume>23</volume><issue>13</issue><spage>6983</spage><epage>6990</epage><pages>6983-6990</pages><issn>0743-7463</issn><eissn>1520-5827</eissn><coden>LANGD5</coden><abstract>A model incorporating a phase angle between an applied electric field and the motion of particles driven by it explains electrolyte-dependent pairwise particle motion near electrodes. The model, predicting that two particles aggregate when this phase angle is greater than 90° but separate when the phase angle is less than 90°, was based largely on contrasting behavior in two electrolytes (KOH and NaHCO3) used with indium tin oxide (ITO) electrodes. The present contribution expands the experimental evidence for this model to KOH, NaHCO3, NaOH, NH4OH, KCl, and H2CO3 solutions with Pt, as well as ITO electrodes. The phase angle correlation was verified in all cases. Comparisons of the model predictions to experimental data show that the sign and order of magnitude of rates of change in the separation distances between particle pairs are correctly predicted.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>17521204</pmid><doi>10.1021/la070049j</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0743-7463 |
| ispartof | Langmuir, 2007-06, Vol.23 (13), p.6983-6990 |
| issn | 0743-7463 1520-5827 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_70606605 |
| source | MEDLINE; American Chemical Society Publications |
| subjects | Chemistry Colloidal state and disperse state Colloids - chemistry Electrodes Electrolytes - chemistry Electromagnetic Fields Exact sciences and technology General and physical chemistry Models, Chemical Surface physical chemistry Tin Compounds |
| title | Electrolyte-Dependent Pairwise Particle Motion near Electrodes at Frequencies below 1 kHz |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-07T15%3A01%3A56IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Electrolyte-Dependent%20Pairwise%20Particle%20Motion%20near%20Electrodes%20at%20Frequencies%20below%201%20kHz&rft.jtitle=Langmuir&rft.au=Hoggard,%20James%20D&rft.date=2007-06-19&rft.volume=23&rft.issue=13&rft.spage=6983&rft.epage=6990&rft.pages=6983-6990&rft.issn=0743-7463&rft.eissn=1520-5827&rft.coden=LANGD5&rft_id=info:doi/10.1021/la070049j&rft_dat=%3Cproquest_cross%3E70606605%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=70606605&rft_id=info:pmid/17521204&rfr_iscdi=true |