Unusual Spin Transition Behavior in 2,6-Bis((pyrazol-3-yl)-pyridine) Iron(II)-bis-oxalato-platinate(II)

[Fe(bpp)2][Pt(ox)2]·H2O (with bpp = 2,6-bis(pyrazol-3-yl)-pyridine and ox = oxalate) was prepared, and its spin crossover behavior was characterized. The two-step spin transition behavior changes over several cycles. The original behavior is restored when the sample is allowed to relax for a week. F...

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Veröffentlicht in:	The journal of physical chemistry. B 2007-06, Vol.111 (24), p.6738-6747
Hauptverfasser:	Grunert, C. Matthias, Goodwin, Harold A, Carbonera, Chiara, Létard, Jean-François, Kusz, Joachim, Gütlich, Philipp
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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