Solute-Stationary Phase Interaction in Gas Liquid Chromatography. Thermodynamic Parameters for Substituted Halogenobenzene Derivatives

Thermodynamic parameters were determined by variable temperature experiments on the gas liquid chromatography (GLC) relative retention values, log γ, of 3- and 4-substituted halogenobenzene derivatives under non-polar condition. These ΔΔHSº(R, X) had a compensational relation with the ΔΔSSº(R, X) va...

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Veröffentlicht in:	Chemical & pharmaceutical bulletin 2001, Vol.49(1), pp.5-9
1. Verfasser:	KAWAKI, Hideko
Format:	Artikel
Sprache:	eng
Schlagworte:	adsorbed active complex Analytical chemistry Benzene Derivatives - chemistry Chemistry Chromatographic methods and physical methods associated with chromatography Chromatography, Gas - methods descriptor σa entropy change ΔΔSºs Exact sciences and technology Gas chromatographic methods gas liquid chromatography Halogens - chemistry retention value logγ substituted halogenobenzene derivative Thermodynamics
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