Kinetic studies of the reaction of hydroxyl radicals with trichloroethylene and tetrachloroethylene

Rate coefficients are reported for the gas-phase reaction of the hydroxyl radical (OH) with C 2HCl 3 ( k 1) and C 2Cl 4 ( k 2) over an extended temperature range at 740±10 Torr in a He bath gas. These absolute rate measurements were accomplished using a laser photolysis/laser-induced fluorescence (L...

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Veröffentlicht in:	Chemosphere (Oxford) 2001-02, Vol.42 (5), p.571-577
Hauptverfasser:	Tichenor, LeAnn B., El-Sinawi, Abdulaziz, Yamada, Takahiro, Taylor, Philip H., Peng, Jingping, Hu, Xiaohua, Marshall, Paul
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Atmospheric pollution Chlorinated hydrocarbons Exact sciences and technology Hydroxyl Kinetics Oxidation, reaction mechanisms Pollutants physicochemistry study: properties, effects, reactions, transport and distribution Pollution tetrachloroethylene trichloroethylene
Online-Zugang:	Volltext
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