Gas-Phase Heats of Formation for Alkylimmonium Cations by Photoionization Mass Spectrometry

Photoionization mass spectrometry has been used to measure appearance energies for immonium cation formation from 25 alkyl amine precursors. A number of the unimolecular fragmentation processes are shown to involve excess energy at threshold so that, of the 11 different cations investigated, it is o...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2007-05, Vol.111 (21), p.4643-4649
1. Verfasser:	Traeger, John C
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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