Use of Anions To Allow Translational Isomerism of a [2]Rotaxane

We report a molecular [2]rotaxane which comprises a molecular cage and a dumbbell‐shaped component, in which translational isomerism can be performed reversibly through an in situ anion exchange process, that is, sequential addition of Bu4NCl/AgPF6 reagent pairs. The [2]rotaxane incorporates two pyr...

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Veröffentlicht in:	Chemistry : a European journal 2007-01, Vol.13 (15), p.4350-4355
Hauptverfasser:	Lin, Chi-Feng, Lai, Chien-Chen, Liu, Yi-Hung, Peng, Shie-Ming, Chiu, Sheng-Hsien
Format:	Artikel
Sprache:	eng
Schlagworte:	anion switch Anions - chemistry host-guest systems Isomerism molecular cages molecular machines Molecular Structure rotaxanes Rotaxanes - chemistry
Online-Zugang:	Volltext
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