Studies of the Kinetics and Thermochemistry of the Forward and Reverse Reaction Cl + C6H6 = HCl + C6H5

The laser flash photolysis resonance fluorescence technique was used to monitor atomic Cl kinetics. Loss of Cl following photolysis of CCl4 and NaCl was used to determine k(Cl + C6H6) = 6.4 × 10-12 exp(−18.1 kJ mol-1/RT) cm3 molecule-1 s-1 over 578−922 K and k(Cl + C6D6) = 6.2 × 10-12 exp(−22.8 kJ m...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2007-05, Vol.111 (19), p.3970-3976
Hauptverfasser:	Alecu, I. M, Gao, Yide, Hsieh, P-C, Sand, Jordan P, Ors, Ahmet, McLeod, A, Marshall, Paul
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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