Varying Acidity of Aqua Ligands in Dependence on the Microenvironment in Mononucleobase (nb) Complexes of Type cis- and trans-[Pt(NH3)2(nb)(H2O)] n

Aqua ligands in mixed aqua/nucleobase metal complexes are potential sites of acid−base catalysis and/or, when present as hydroxo ligands, can directly be involved in hydrolysis reactions. pK a values of close to 7 are consequently of particular interest and potential significance. Here we report on...

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Veröffentlicht in:	Inorganic chemistry 2007-05, Vol.46 (10), p.4036-4043
Hauptverfasser:	Lax, Patrick M, Garijo Añorbe, Marta, Müller, Barbara, Bivián-Castro, Egla Yareth, Lippert, Bernhard
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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