Organic n-Channel Transistors Based on Core-Cyanated Perylene Carboxylic Diimide Derivatives
Five core-cyanated perylene carboxylic diimides end-functionalized with fluorine-containing linear and cyclic substituents have been synthesized and employed in the fabrication of air-stable n-channel organic thin-film field-effect transistors with carrier mobilities up to 0.1 cm2/Vs. The relationsh...
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| Veröffentlicht in: | Journal of the American Chemical Society 2008-04, Vol.130 (14), p.4637-4645 |
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| container_title | Journal of the American Chemical Society |
| container_volume | 130 |
| creator | Weitz, R. Thomas Amsharov, Konstantin Zschieschang, Ute Villas, Esther Barrena Goswami, Dipak K Burghard, Marko Dosch, Helmut Jansen, Martin Kern, Klaus Klauk, Hagen |
| description | Five core-cyanated perylene carboxylic diimides end-functionalized with fluorine-containing linear and cyclic substituents have been synthesized and employed in the fabrication of air-stable n-channel organic thin-film field-effect transistors with carrier mobilities up to 0.1 cm2/Vs. The relationships between molecular structure, thin-film morphology, substrate temperature during vacuum deposition, transistor performance, and air stability have been investigated. Our experiments led us to conclude that the role of the fluorine functionalization in the air-stable n-channel operation of the transistors is different than previously thought. |
| doi_str_mv | 10.1021/ja074675e |
| format | Article |
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Thomas ; Amsharov, Konstantin ; Zschieschang, Ute ; Villas, Esther Barrena ; Goswami, Dipak K ; Burghard, Marko ; Dosch, Helmut ; Jansen, Martin ; Kern, Klaus ; Klauk, Hagen</creator><creatorcontrib>Weitz, R. Thomas ; Amsharov, Konstantin ; Zschieschang, Ute ; Villas, Esther Barrena ; Goswami, Dipak K ; Burghard, Marko ; Dosch, Helmut ; Jansen, Martin ; Kern, Klaus ; Klauk, Hagen</creatorcontrib><description>Five core-cyanated perylene carboxylic diimides end-functionalized with fluorine-containing linear and cyclic substituents have been synthesized and employed in the fabrication of air-stable n-channel organic thin-film field-effect transistors with carrier mobilities up to 0.1 cm2/Vs. The relationships between molecular structure, thin-film morphology, substrate temperature during vacuum deposition, transistor performance, and air stability have been investigated. 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| source | ACS Publications |
| title | Organic n-Channel Transistors Based on Core-Cyanated Perylene Carboxylic Diimide Derivatives |
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