Electronic spectra of jet-cooled calix[4]arene and its van der Waals clusters: Encapsulation of a neutral atom in a molecular bowl

Electronic spectra of jet-cooled calix[4]arene and its van der Waals clusters: Encapsulation of a neutral atom in a molecular bowl

The encapsulation of neutral guest has been studied for calix[4]arene (C4A) by forming van der Waals clusters with Ar and Ne in supersonic jets. The electronic transitions of these clusters suggest that the first Ar (Ne) is encapsulated inside the C4A cavity, while the next atoms are bound outside.

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Veröffentlicht in:The Journal of chemical physics 2007-04, Vol.126 (14), p.141101-141101-4
Hauptverfasser: Ebata, Takayuki, Hodono, Yuki, Ito, Takafumi, Inokuchi, Yoshiya
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container_end_page 141101-4
container_issue 14
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container_title The Journal of chemical physics
container_volume 126
creator Ebata, Takayuki
Hodono, Yuki
Ito, Takafumi
Inokuchi, Yoshiya
description The encapsulation of neutral guest has been studied for calix[4]arene (C4A) by forming van der Waals clusters with Ar and Ne in supersonic jets. The electronic transitions of these clusters suggest that the first Ar (Ne) is encapsulated inside the C4A cavity, while the next atoms are bound outside.
doi_str_mv 10.1063/1.2723068
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title Electronic spectra of jet-cooled calix[4]arene and its van der Waals clusters: Encapsulation of a neutral atom in a molecular bowl
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