Transforming Surface Coordination Polymers into Covalent Surface Polymers: Linked Polycondensed Aromatics through Oligomerization of N-Heterocyclic Carbene Intermediates

Transforming Surface Coordination Polymers into Covalent Surface Polymers: Linked Polycondensed Aromatics through Oligomerization of N-Heterocyclic Carbene Intermediates

Isomerize and polymerize! Thermally induced tautomerization of the N‐heteropolycyclic 1,3,8,10‐tetraazaperopyrene to a Wanzlick‐type carbene intermediate on a Cu(111) surface leads to covalently linked polyaromatic chains, which can be mechanically manipulated. The pictures show the respective struc...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2008-03, Vol.47 (13), p.2414-2417
Hauptverfasser: Matena, Manfred, Riehm, Till, Stöhr, Meike, Jung, Thomas A, Gade, Lutz H
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Sprache:eng
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N-heterocyclic carbenes
polycyclic aromatic hydrocarbons
scanning probe microscopy
surface chemistry
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container_issue 13
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container_title Angewandte Chemie (International ed.)
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creator Matena, Manfred
Riehm, Till
Stöhr, Meike
Jung, Thomas A
Gade, Lutz H
description Isomerize and polymerize! Thermally induced tautomerization of the N‐heteropolycyclic 1,3,8,10‐tetraazaperopyrene to a Wanzlick‐type carbene intermediate on a Cu(111) surface leads to covalently linked polyaromatic chains, which can be mechanically manipulated. The pictures show the respective structures superimposed on the STM images.
doi_str_mv 10.1002/anie.200704072
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source Wiley Online Library Journals Frontfile Complete
subjects N-heterocyclic carbenes
polycyclic aromatic hydrocarbons
scanning probe microscopy
surface chemistry
title Transforming Surface Coordination Polymers into Covalent Surface Polymers: Linked Polycondensed Aromatics through Oligomerization of N-Heterocyclic Carbene Intermediates
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